<HashMap><database>biostudies-literature</database><scores/><additional><omics_type>Unknown</omics_type><volume>65(Pt 1)</volume><submitter>Tang ZH</submitter><pubmed_abstract>The asymmetric unit of the title compound, C(5)H(12)N(+)·C(14)H(8)BO(6) (-) or [C(5)H(12)N][BO(4)(C(7)H(4)O)(2)], contains two piperidinium cations and two bis-(salicylato)borate anions. The coordination geometries around the B atoms are distorted tetra-hedral. In the two mol-ecules, the aromatic rings are oriented at dihedral angles of 76.27 (3) and 83.86 (3)°. The rings containing B atoms have twist-boat conformations, while the two cations adopt chair conformations. In the crystal, the component species are linked by N-H⋯O hydrogen bonds. In the crystal structure, intra- and inter-molecular N-H⋯O hydrogen bonds link the mol-ecules.</pubmed_abstract><journal>Acta crystallographica. Section E, Structure reports online</journal><pagination>o171</pagination><full_dataset_link>https://www.ebi.ac.uk/biostudies/studies/S-EPMC2968082</full_dataset_link><repository>biostudies-literature</repository><pubmed_title>Piperidinium bis-(2-oxidobenzoato-κO,O)borate.</pubmed_title><pmcid>PMC2968082</pmcid><pubmed_authors>Huang C</pubmed_authors><pubmed_authors>Tang ZH</pubmed_authors></additional><is_claimable>false</is_claimable><name>Piperidinium bis-(2-oxidobenzoato-κO,O)borate.</name><description>The asymmetric unit of the title compound, C(5)H(12)N(+)·C(14)H(8)BO(6) (-) or [C(5)H(12)N][BO(4)(C(7)H(4)O)(2)], contains two piperidinium cations and two bis-(salicylato)borate anions. The coordination geometries around the B atoms are distorted tetra-hedral. In the two mol-ecules, the aromatic rings are oriented at dihedral angles of 76.27 (3) and 83.86 (3)°. The rings containing B atoms have twist-boat conformations, while the two cations adopt chair conformations. In the crystal, the component species are linked by N-H⋯O hydrogen bonds. In the crystal structure, intra- and inter-molecular N-H⋯O hydrogen bonds link the mol-ecules.</description><dates><release>2008-01-01T00:00:00Z</release><publication>2008 Dec</publication><modification>2025-04-18T14:09:52.398Z</modification><creation>2019-03-27T00:00:04Z</creation></dates><accession>S-EPMC2968082</accession><cross_references><pubmed>21581628</pubmed><doi>10.1107/S1600536808042608</doi></cross_references></HashMap>