{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["65(Pt 2)"],"submitter":["Chang JL"],"pubmed_abstract":["In the crystal structure of the title compound, [Mn(N(3))(2)(C(10)H(14)N(3)O(2)S)(2)], the Mn(II) atom exhibits a roughly octa-hedral coordination geometry. The Mn(II) atom lies on an inversion centre, thus the asymmetric unit comprises one half-mol-ecule. The metal center is six-coordinated by two azide anions and by two chelating 4,4,5,5-tetra-methyl-2-(1,3-thia-zol-2-yl)-2-imidazoline-1-oxyl-3-oxide nitronyl nitroxide radical ligands, leading to two six-membered chelate rings."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["m181"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC2968124"],"repository":["biostudies-literature"],"pubmed_title":["Diazido-bis[4,4,5,5-tetra-methyl-2-(1,3-thia-zol-2-yl)-2-imidazoline-1-oxyl-3-oxide-κO,N]manganese(II)."],"pmcid":["PMC2968124"],"pubmed_authors":["Jiang K","Chang JL","Gao ZY"],"additional_accession":[]},"is_claimable":false,"name":"Diazido-bis[4,4,5,5-tetra-methyl-2-(1,3-thia-zol-2-yl)-2-imidazoline-1-oxyl-3-oxide-κO,N]manganese(II).","description":"In the crystal structure of the title compound, [Mn(N(3))(2)(C(10)H(14)N(3)O(2)S)(2)], the Mn(II) atom exhibits a roughly octa-hedral coordination geometry. The Mn(II) atom lies on an inversion centre, thus the asymmetric unit comprises one half-mol-ecule. The metal center is six-coordinated by two azide anions and by two chelating 4,4,5,5-tetra-methyl-2-(1,3-thia-zol-2-yl)-2-imidazoline-1-oxyl-3-oxide nitronyl nitroxide radical ligands, leading to two six-membered chelate rings.","dates":{"release":"2009-01-01T00:00:00Z","publication":"2009 Jan","modification":"2025-04-18T14:10:28.697Z","creation":"2019-03-27T00:00:51Z"},"accession":"S-EPMC2968124","cross_references":{"pubmed":["21581785"],"doi":["10.1107/S1600536809000786"]}}