biostudies-literatureUnknown65(Pt 2)Chang JLIn the crystal structure of the title compound, [Mn(N(3))(2)(C(10)H(14)N(3)O(2)S)(2)], the Mn(II) atom exhibits a roughly octa-hedral coordination geometry. The Mn(II) atom lies on an inversion centre, thus the asymmetric unit comprises one half-mol-ecule. The metal center is six-coordinated by two azide anions and by two chelating 4,4,5,5-tetra-methyl-2-(1,3-thia-zol-2-yl)-2-imidazoline-1-oxyl-3-oxide nitronyl nitroxide radical ligands, leading to two six-membered chelate rings.Acta crystallographica. Section E, Structure reports onlinem181https://www.ebi.ac.uk/biostudies/studies/S-EPMC2968124biostudies-literatureDiazido-bis[4,4,5,5-tetra-methyl-2-(1,3-thia-zol-2-yl)-2-imidazoline-1-oxyl-3-oxide-κO,N]manganese(II).PMC2968124Jiang KChang JLGao ZYfalseDiazido-bis[4,4,5,5-tetra-methyl-2-(1,3-thia-zol-2-yl)-2-imidazoline-1-oxyl-3-oxide-κO,N]manganese(II).In the crystal structure of the title compound, [Mn(N(3))(2)(C(10)H(14)N(3)O(2)S)(2)], the Mn(II) atom exhibits a roughly octa-hedral coordination geometry. The Mn(II) atom lies on an inversion centre, thus the asymmetric unit comprises one half-mol-ecule. The metal center is six-coordinated by two azide anions and by two chelating 4,4,5,5-tetra-methyl-2-(1,3-thia-zol-2-yl)-2-imidazoline-1-oxyl-3-oxide nitronyl nitroxide radical ligands, leading to two six-membered chelate rings.2009-01-01T00:00:00Z2009 Jan2025-04-18T14:10:28.697Z2019-03-27T00:00:51ZS-EPMC29681242158178510.1107/S1600536809000786