{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["65(Pt 2)"],"submitter":["Ji Z"],"pubmed_abstract":["The title compound, [Cu(C(2)O(4))(2)(C(6)H(14)NO)(2)], was synthesized by mixing diacetonamine hydrogen oxalate and copper sulfate in ethanol/water. The mol-ecule is centrosymmetric, so two pairs of equivalent ligands lie trans to each other. The Cu(II) center, located on a position with 2/m site symmetry, is six-coordinated by four O atoms from two oxalate ligands at short distances and the carbonyl O atoms from the 4-amino-4-methyl-pentan-2-one ligands at longer distances. Mol-ecules are linked through inter-molecular N-H⋯O hydrogen bonds between the amino groups and carbonyl O atoms; no intra-molecular hydrogen bonds are formed."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["m182"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC2968265"],"repository":["biostudies-literature"],"pubmed_title":["Bis(4-ammonio-4-methyl-pentan-2-one-κO)dioxalato-κO,O-copper(II)."],"pmcid":["PMC2968265"],"pubmed_authors":["Wei S","Ji Z","Wu W"],"additional_accession":[]},"is_claimable":false,"name":"Bis(4-ammonio-4-methyl-pentan-2-one-κO)dioxalato-κO,O-copper(II).","description":"The title compound, [Cu(C(2)O(4))(2)(C(6)H(14)NO)(2)], was synthesized by mixing diacetonamine hydrogen oxalate and copper sulfate in ethanol/water. The mol-ecule is centrosymmetric, so two pairs of equivalent ligands lie trans to each other. The Cu(II) center, located on a position with 2/m site symmetry, is six-coordinated by four O atoms from two oxalate ligands at short distances and the carbonyl O atoms from the 4-amino-4-methyl-pentan-2-one ligands at longer distances. Mol-ecules are linked through inter-molecular N-H⋯O hydrogen bonds between the amino groups and carbonyl O atoms; no intra-molecular hydrogen bonds are formed.","dates":{"release":"2009-01-01T00:00:00Z","publication":"2009 Jan","modification":"2025-04-04T19:42:39.702Z","creation":"2019-03-27T00:00:05Z"},"accession":"S-EPMC2968265","cross_references":{"pubmed":["21581786"],"doi":["10.1107/S1600536808042396"]}}