<HashMap><database>biostudies-literature</database><scores/><additional><omics_type>Unknown</omics_type><volume>65(Pt 2)</volume><submitter>Ji Z</submitter><pubmed_abstract>The title compound, [Cu(C(2)O(4))(2)(C(6)H(14)NO)(2)], was synthesized by mixing diacetonamine hydrogen oxalate and copper sulfate in ethanol/water. The mol-ecule is centrosymmetric, so two pairs of equivalent ligands lie trans to each other. The Cu(II) center, located on a position with 2/m site symmetry, is six-coordinated by four O atoms from two oxalate ligands at short distances and the carbonyl O atoms from the 4-amino-4-methyl-pentan-2-one ligands at longer distances. Mol-ecules are linked through inter-molecular N-H⋯O hydrogen bonds between the amino groups and carbonyl O atoms; no intra-molecular hydrogen bonds are formed.</pubmed_abstract><journal>Acta crystallographica. Section E, Structure reports online</journal><pagination>m182</pagination><full_dataset_link>https://www.ebi.ac.uk/biostudies/studies/S-EPMC2968265</full_dataset_link><repository>biostudies-literature</repository><pubmed_title>Bis(4-ammonio-4-methyl-pentan-2-one-κO)dioxalato-κO,O-copper(II).</pubmed_title><pmcid>PMC2968265</pmcid><pubmed_authors>Wei S</pubmed_authors><pubmed_authors>Ji Z</pubmed_authors><pubmed_authors>Wu W</pubmed_authors></additional><is_claimable>false</is_claimable><name>Bis(4-ammonio-4-methyl-pentan-2-one-κO)dioxalato-κO,O-copper(II).</name><description>The title compound, [Cu(C(2)O(4))(2)(C(6)H(14)NO)(2)], was synthesized by mixing diacetonamine hydrogen oxalate and copper sulfate in ethanol/water. The mol-ecule is centrosymmetric, so two pairs of equivalent ligands lie trans to each other. The Cu(II) center, located on a position with 2/m site symmetry, is six-coordinated by four O atoms from two oxalate ligands at short distances and the carbonyl O atoms from the 4-amino-4-methyl-pentan-2-one ligands at longer distances. Mol-ecules are linked through inter-molecular N-H⋯O hydrogen bonds between the amino groups and carbonyl O atoms; no intra-molecular hydrogen bonds are formed.</description><dates><release>2009-01-01T00:00:00Z</release><publication>2009 Jan</publication><modification>2025-04-04T19:42:39.702Z</modification><creation>2019-03-27T00:00:05Z</creation></dates><accession>S-EPMC2968265</accession><cross_references><pubmed>21581786</pubmed><doi>10.1107/S1600536808042396</doi></cross_references></HashMap>