<HashMap><database>biostudies-literature</database><scores/><additional><omics_type>Unknown</omics_type><volume>65(Pt 2)</volume><submitter>Lee SM</submitter><pubmed_abstract>In the title ion-pair, C(22)H(29)Cl(2)N(4)O(2) (+)·C(2)F(3)O(2) (-), ammonium-carboxyl-ate N-H⋯O hydrogen bonds link two cations and two anions about a centre of inversion to generate a hydrogen-bonded tetramer. In the cation, one of the imino N atoms is protonated and donates a hydrogen bond to the O atom of the adjacent chloro-phenyl ring. The other imino N atom acts as a hydrogen-bond acceptor from a phenolate O atom.</pubmed_abstract><journal>Acta crystallographica. Section E, Structure reports online</journal><pagination>o410</pagination><full_dataset_link>https://www.ebi.ac.uk/biostudies/studies/S-EPMC2968282</full_dataset_link><repository>biostudies-literature</repository><pubmed_title>2-{1-[2-((2-Ammonio-ethyl){2-[1-(5-chloro-2-hydroxy-phen-yl)ethyl-idene-amino]eth-yl}amino)ethyl-iminio]eth-yl}-4-chloro-phenolate trifluoro-acetate.</pubmed_title><pmcid>PMC2968282</pmcid><pubmed_authors>Lee SM</pubmed_authors><pubmed_authors>Ng SW</pubmed_authors><pubmed_authors>Ali HM</pubmed_authors><pubmed_authors>Lo KM</pubmed_authors></additional><is_claimable>false</is_claimable><name>2-{1-[2-((2-Ammonio-ethyl){2-[1-(5-chloro-2-hydroxy-phen-yl)ethyl-idene-amino]eth-yl}amino)ethyl-iminio]eth-yl}-4-chloro-phenolate trifluoro-acetate.</name><description>In the title ion-pair, C(22)H(29)Cl(2)N(4)O(2) (+)·C(2)F(3)O(2) (-), ammonium-carboxyl-ate N-H⋯O hydrogen bonds link two cations and two anions about a centre of inversion to generate a hydrogen-bonded tetramer. In the cation, one of the imino N atoms is protonated and donates a hydrogen bond to the O atom of the adjacent chloro-phenyl ring. The other imino N atom acts as a hydrogen-bond acceptor from a phenolate O atom.</description><dates><release>2009-01-01T00:00:00Z</release><publication>2009 Jan</publication><modification>2025-04-04T19:42:45.077Z</modification><creation>2019-03-27T00:00:05Z</creation></dates><accession>S-EPMC2968282</accession><cross_references><pubmed>21582002</pubmed><doi>10.1107/S1600536809002943</doi></cross_references></HashMap>