{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["65(Pt 3)"],"submitter":["Wriedt M"],"pubmed_abstract":["In the crystal structure of the title compound, [Fe(3)(NCS)(6)(C(4)H(4)N(2))(8)](n), each iron(II) cation is coordinated by four N-bonded pyrimidine ligands and two N-bonded thio-cyanate anions in a distorted octa-hedral environment. The asymmetric unit consists of one iron cation located on a crystallographic center of inversion, as well as one iron cation, three thio-cyanate anions and four pyrimidine ligands occupying general positions. The structure consists of square secondary building units (SBUs) with an Fe atom at each corner, which are μ-N(1):N(3)-bridged by the pyrimidine ligands. The SBUs are linked into infinite chains running in the c-axis direction via common opposite corners."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["m296-7"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC2968508"],"repository":["biostudies-literature"],"pubmed_title":["catena-Poly[bis-[cis-dipyrimidine-trans-dithio-cyanato-iron(II)]-di-μ-pyrimidine-[trans-dithio-cyanato-iron(II)]-di-μ-pyrimidine]."],"pmcid":["PMC2968508"],"pubmed_authors":["Wriedt M","Nather C","Sellmer S","Jess I"],"additional_accession":[]},"is_claimable":false,"name":"catena-Poly[bis-[cis-dipyrimidine-trans-dithio-cyanato-iron(II)]-di-μ-pyrimidine-[trans-dithio-cyanato-iron(II)]-di-μ-pyrimidine].","description":"In the crystal structure of the title compound, [Fe(3)(NCS)(6)(C(4)H(4)N(2))(8)](n), each iron(II) cation is coordinated by four N-bonded pyrimidine ligands and two N-bonded thio-cyanate anions in a distorted octa-hedral environment. The asymmetric unit consists of one iron cation located on a crystallographic center of inversion, as well as one iron cation, three thio-cyanate anions and four pyrimidine ligands occupying general positions. The structure consists of square secondary building units (SBUs) with an Fe atom at each corner, which are μ-N(1):N(3)-bridged by the pyrimidine ligands. The SBUs are linked into infinite chains running in the c-axis direction via common opposite corners.","dates":{"release":"2009-01-01T00:00:00Z","publication":"2009 Feb","modification":"2025-04-19T21:12:29.75Z","creation":"2019-03-27T00:00:06Z"},"accession":"S-EPMC2968508","cross_references":{"pubmed":["21582078"],"doi":["10.1107/S1600536809005509"]}}