{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["65(Pt 4)"],"submitter":["Le Bail A"],"pubmed_abstract":["The title compound, octaaqua-(hydrogenfluorido)dicopper(II) hexa-fluoridoferrate(III) dihydrate, was synthesized under hydro-thermal conditions. The Cu atom is coordinated by one F and five O atoms within a highly distorted octa-hedron, forming dimeric [Cu(2)(H(2)O)(8)HF(2)](3+) units by edge sharing. These units are hydrogen bonded to [FeF(6)](3-) anions and to an inter-stitial water mol-ecule. The former feature Fe(3+) on a special position (). The dimeric copper units are linked to adjacent dimers by F-H⋯F hydrogen bonds. Additional O-H⋯O and O-H⋯F hydrogen bonds help to consolidate the crystal packing."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["i23-i24"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC2968889"],"repository":["biostudies-literature"],"pubmed_title":["[Cu(2)(HF(2))(H(2)O)(8)][FeF(6)]·2H(2)O."],"pmcid":["PMC2968889"],"pubmed_authors":["Mercier AM","Le Bail A"],"additional_accession":[]},"is_claimable":false,"name":"[Cu(2)(HF(2))(H(2)O)(8)][FeF(6)]·2H(2)O.","description":"The title compound, octaaqua-(hydrogenfluorido)dicopper(II) hexa-fluoridoferrate(III) dihydrate, was synthesized under hydro-thermal conditions. The Cu atom is coordinated by one F and five O atoms within a highly distorted octa-hedron, forming dimeric [Cu(2)(H(2)O)(8)HF(2)](3+) units by edge sharing. These units are hydrogen bonded to [FeF(6)](3-) anions and to an inter-stitial water mol-ecule. The former feature Fe(3+) on a special position (). The dimeric copper units are linked to adjacent dimers by F-H⋯F hydrogen bonds. Additional O-H⋯O and O-H⋯F hydrogen bonds help to consolidate the crystal packing.","dates":{"release":"2009-01-01T00:00:00Z","publication":"2009 Mar","modification":"2025-04-03T22:21:49.63Z","creation":"2019-03-27T00:00:07Z"},"accession":"S-EPMC2968889","cross_references":{"pubmed":["21582307"],"doi":["10.1107/S1600536809006874"]}}