biostudies-literatureUnknown65(Pt 7)Revathi CThe title compound, trans-[Co(C(4)H(7)N(2)O(2))(2)Cl(C(10)H(14)N(2)S)]·0.5H(2)O, contains two independent mol-ecules in the asymmetric unit in which the Co(III) ions are coordinated in slightly distorted octa-hedral coordination environments. The bis-chelating glyoximate ligands, which occupy equatorial sites, are linked by interligand O-H⋯O hydrogen bonds. The dihedral angles between the mean planes of the glyoximate ligands in each mol-ecule are 2.07 (8) and 1.60 (1)°. The asymmetric unit contains a solvent water mol-ecule which is disordered over two sites with refined occupancies 0.64 (2) and 0.36 (2).Acta crystallographica. Section E, Structure reports onlinem795-6https://www.ebi.ac.uk/biostudies/studies/S-EPMC2969215biostudies-literature(N-n-Butyl-pyridine-4-carbothio-amide-κN)chloridobis(dimethyl-glyoximato-κN,N')cobalt(III) hemihydrate.PMC2969215Revathi CDayalan ASethusankar Kfalse(N-n-Butyl-pyridine-4-carbothio-amide-κN)chloridobis(dimethyl-glyoximato-κN,N')cobalt(III) hemihydrate.The title compound, trans-[Co(C(4)H(7)N(2)O(2))(2)Cl(C(10)H(14)N(2)S)]·0.5H(2)O, contains two independent mol-ecules in the asymmetric unit in which the Co(III) ions are coordinated in slightly distorted octa-hedral coordination environments. The bis-chelating glyoximate ligands, which occupy equatorial sites, are linked by interligand O-H⋯O hydrogen bonds. The dihedral angles between the mean planes of the glyoximate ligands in each mol-ecule are 2.07 (8) and 1.60 (1)°. The asymmetric unit contains a solvent water mol-ecule which is disordered over two sites with refined occupancies 0.64 (2) and 0.36 (2).2009-01-01T00:00:00Z2009 Jun2025-04-04T21:05:12.765Z2019-03-27T00:00:52ZS-EPMC29692152158272210.1107/S1600536809022661