<HashMap><database>biostudies-literature</database><scores/><additional><omics_type>Unknown</omics_type><volume>65(Pt 7)</volume><submitter>Alizadeh R</submitter><pubmed_abstract>In the mol-ecule of the title compound, [Hg(NCS)(2)(C(26)H(20)N(2))], the Hg(II) atom is four-coordinated in a distorted tetra-hedral configuration by two N atoms from a chelating 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline ligand and by two S atoms from two thio-cyanate anions. The ligand ring system is not planar. The dihedral angle between the phenyl rings is 53.20 (3)° . In the crystal structure, π-π contacts between phenanthroline rings [centroid-centroid distance = 3.981 (1) Å] may stabilize the structure.</pubmed_abstract><journal>Acta crystallographica. Section E, Structure reports online</journal><pagination>m817-8</pagination><full_dataset_link>https://www.ebi.ac.uk/biostudies/studies/S-EPMC2969232</full_dataset_link><repository>biostudies-literature</repository><pubmed_title>(2,9-Dimethyl-4,7-diphenyl-1,10-phen-anthroline-κN,N')bis-(thio-cyanato-κS)mercury(II).</pubmed_title><pmcid>PMC2969232</pmcid><pubmed_authors>Alizadeh R</pubmed_authors></additional><is_claimable>false</is_claimable><name>(2,9-Dimethyl-4,7-diphenyl-1,10-phen-anthroline-κN,N')bis-(thio-cyanato-κS)mercury(II).</name><description>In the mol-ecule of the title compound, [Hg(NCS)(2)(C(26)H(20)N(2))], the Hg(II) atom is four-coordinated in a distorted tetra-hedral configuration by two N atoms from a chelating 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline ligand and by two S atoms from two thio-cyanate anions. The ligand ring system is not planar. The dihedral angle between the phenyl rings is 53.20 (3)° . In the crystal structure, π-π contacts between phenanthroline rings [centroid-centroid distance = 3.981 (1) Å] may stabilize the structure.</description><dates><release>2009-01-01T00:00:00Z</release><publication>2009 Jun</publication><modification>2025-04-04T21:04:49.177Z</modification><creation>2019-03-27T00:00:52Z</creation></dates><accession>S-EPMC2969232</accession><cross_references><pubmed>21582740</pubmed><doi>10.1107/S1600536809023228</doi></cross_references></HashMap>