{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["65(Pt 7)"],"submitter":["Randeniya SR"],"pubmed_abstract":["The title complex, [Ni(NCS)(2)(C(18)H(18)N(4))]·0.5CH(3)OH, consists of two crystallographically distinct complexes and a methanol solvent mol-ecule. The Ni(II) complexes are pseudo-octa-hedral six-coordinate, with the tris-(2-pyridylmeth-yl)amine (TPA) ligand providing four N atoms and two N-bound thio-cyanates providing the final two N atoms. The distances and angles are typical for Ni(II)-TPA complexes. The compound has unit-cell parameters that are surprisingly similar to the previously reported hydrate."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["m771"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC2969451"],"repository":["biostudies-literature"],"pubmed_title":["Bis(thio-cyanato-?N)[tris-(2-pyridylmeth-yl)amine-?N,N',N'',N''']nickel(II) methanol hemisolvate."],"pmcid":["PMC2969451"],"pubmed_authors":["Randeniya SR","Norman RE"],"additional_accession":[]},"is_claimable":false,"name":"Bis(thio-cyanato-?N)[tris-(2-pyridylmeth-yl)amine-?N,N',N'',N''']nickel(II) methanol hemisolvate.","description":"The title complex, [Ni(NCS)(2)(C(18)H(18)N(4))]·0.5CH(3)OH, consists of two crystallographically distinct complexes and a methanol solvent mol-ecule. The Ni(II) complexes are pseudo-octa-hedral six-coordinate, with the tris-(2-pyridylmeth-yl)amine (TPA) ligand providing four N atoms and two N-bound thio-cyanates providing the final two N atoms. The distances and angles are typical for Ni(II)-TPA complexes. The compound has unit-cell parameters that are surprisingly similar to the previously reported hydrate.","dates":{"release":"2009-01-01T00:00:00Z","publication":"2009 Jun","modification":"2021-02-21T06:57:26Z","creation":"2019-03-27T00:00:10Z"},"accession":"S-EPMC2969451","cross_references":{"pubmed":["21582701"],"doi":["10.1107/S1600536809021722"]}}