{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Zhang J"],"funding":["NCCIH NIH HHS"],"pagination":["m1136"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC2970141"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["65(Pt 9)"],"pubmed_abstract":["The title compound, [Cu(2)(C(14)H(13)N(2)O)(2)(N(3))(2)], was synthesized by the reaction of Cu(NO(3))(2)·3H(2)O with the Schiff base 2-[1-(2-pyridylmethyl-imino)eth-yl]phenol (HL) in methanol-water solution, adding NaN(3) as the bridging ligand. The asymmetric unit contains one half-mol-ecule, the other half being generated by the inversion center. Each Cu(II) atom shows a slightly distorted trigonal-pyramidal geometry formed by two N atoms and one O atom from one Schiff base ligand, by another O atom of a second Schiff base ligand and by an azide N atom. The crystal structure is stabilized by intermolecular C-H⋯N hydrogen bonds."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pubmed_title":["Bis{μ-2-[1-(2-Pyridylmethyl-imino)eth-yl]phenolato}bis-[azido-copper(II)]."],"pmcid":["PMC2970141"],"funding_grant_id":["F31 AT002842"],"pubmed_authors":["Zhang HH","Zhang J","Chen XD","Sun BW"],"additional_accession":[]},"is_claimable":false,"name":"Bis{μ-2-[1-(2-Pyridylmethyl-imino)eth-yl]phenolato}bis-[azido-copper(II)].","description":"The title compound, [Cu(2)(C(14)H(13)N(2)O)(2)(N(3))(2)], was synthesized by the reaction of Cu(NO(3))(2)·3H(2)O with the Schiff base 2-[1-(2-pyridylmethyl-imino)eth-yl]phenol (HL) in methanol-water solution, adding NaN(3) as the bridging ligand. The asymmetric unit contains one half-mol-ecule, the other half being generated by the inversion center. Each Cu(II) atom shows a slightly distorted trigonal-pyramidal geometry formed by two N atoms and one O atom from one Schiff base ligand, by another O atom of a second Schiff base ligand and by an azide N atom. The crystal structure is stabilized by intermolecular C-H⋯N hydrogen bonds.","dates":{"release":"2009-01-01T00:00:00Z","publication":"2009 Aug","modification":"2025-04-18T19:29:04.708Z","creation":"2019-03-27T00:00:13Z"},"accession":"S-EPMC2970141","cross_references":{"pubmed":["21577473"],"doi":["10.1107/S1600536809030475"]}}