{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["65(Pt 10)"],"submitter":["Surdykowski A"],"pubmed_abstract":["In the crystal structure of the title compound, [Co(C(3)H(4)N(2))(6)](PF(6))(3)·6H(2)O, the Co(III) atom lies on a special position with site-symmetry and the P atom is located on a special position with site symmetry . The Co(III) atom has an almost ideal octa-hedral coordination formed by the N atoms of six imidazole ligands. The water mol-ecules form hydrogen-bonded helical chains propagating in [001] by O-H⋯O inter-actions with a distance of 2.913 (2) Å. They simultaneously inter-act as hydrogen-bond acceptors and donors with the cations and anions, respectively, resulting in the formation of a three-dimensional assembly. Weak C-H⋯F inter-actions further stabilize the crystal structure."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["m1256-7"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC2970253"],"repository":["biostudies-literature"],"pubmed_title":["Hexakis(1H-imidazole-κN)cobalt(III) tris-(hexa-fluoridophosphate) hexa-hydrate."],"pmcid":["PMC2970253"],"pubmed_authors":["Surdykowski A","Szlyk E","Leczkowska A","Dobrzanska L"],"additional_accession":[]},"is_claimable":false,"name":"Hexakis(1H-imidazole-κN)cobalt(III) tris-(hexa-fluoridophosphate) hexa-hydrate.","description":"In the crystal structure of the title compound, [Co(C(3)H(4)N(2))(6)](PF(6))(3)·6H(2)O, the Co(III) atom lies on a special position with site-symmetry and the P atom is located on a special position with site symmetry . The Co(III) atom has an almost ideal octa-hedral coordination formed by the N atoms of six imidazole ligands. The water mol-ecules form hydrogen-bonded helical chains propagating in [001] by O-H⋯O inter-actions with a distance of 2.913 (2) Å. They simultaneously inter-act as hydrogen-bond acceptors and donors with the cations and anions, respectively, resulting in the formation of a three-dimensional assembly. Weak C-H⋯F inter-actions further stabilize the crystal structure.","dates":{"release":"2009-01-01T00:00:00Z","publication":"2009 Sep","modification":"2025-04-19T21:13:57.649Z","creation":"2019-03-27T00:00:14Z"},"accession":"S-EPMC2970253","cross_references":{"pubmed":["21577770"],"doi":["10.1107/S160053680903863X"]}}