biostudies-literatureUnknown65(Pt 10)Surdykowski AIn the crystal structure of the title compound, [Co(C(3)H(4)N(2))(6)](PF(6))(3)·6H(2)O, the Co(III) atom lies on a special position with site-symmetry and the P atom is located on a special position with site symmetry . The Co(III) atom has an almost ideal octa-hedral coordination formed by the N atoms of six imidazole ligands. The water mol-ecules form hydrogen-bonded helical chains propagating in [001] by O-H⋯O inter-actions with a distance of 2.913 (2) Å. They simultaneously inter-act as hydrogen-bond acceptors and donors with the cations and anions, respectively, resulting in the formation of a three-dimensional assembly. Weak C-H⋯F inter-actions further stabilize the crystal structure.Acta crystallographica. Section E, Structure reports onlinem1256-7https://www.ebi.ac.uk/biostudies/studies/S-EPMC2970253biostudies-literatureHexakis(1H-imidazole-κN)cobalt(III) tris-(hexa-fluoridophosphate) hexa-hydrate.PMC2970253Surdykowski ASzlyk ELeczkowska ADobrzanska LfalseHexakis(1H-imidazole-κN)cobalt(III) tris-(hexa-fluoridophosphate) hexa-hydrate.In the crystal structure of the title compound, [Co(C(3)H(4)N(2))(6)](PF(6))(3)·6H(2)O, the Co(III) atom lies on a special position with site-symmetry and the P atom is located on a special position with site symmetry . The Co(III) atom has an almost ideal octa-hedral coordination formed by the N atoms of six imidazole ligands. The water mol-ecules form hydrogen-bonded helical chains propagating in [001] by O-H⋯O inter-actions with a distance of 2.913 (2) Å. They simultaneously inter-act as hydrogen-bond acceptors and donors with the cations and anions, respectively, resulting in the formation of a three-dimensional assembly. Weak C-H⋯F inter-actions further stabilize the crystal structure.2009-01-01T00:00:00Z2009 Sep2025-04-19T21:13:57.649Z2019-03-27T00:00:14ZS-EPMC29702532157777010.1107/S160053680903863X