{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["65(Pt 11)"],"submitter":["Kitiphaisalnont P"],"pubmed_abstract":["In the title compound, [Cu(4)(C(4)H(4)O(4))(2)(C(12)H(8)N(2))(4)(H(2)O)(4)](NO(3))(4)·4H(2)O, the complete tetra-cation is generated by crystallographic inversion symmetry. Both unique Cu(2+) ions are coordinated by an N,N'-bidentate phenanthroline mol-ecule, two O-monodentate bis-bridging succinate dianions and a water mol-ecule, resulting in distorted CuN(2)O(3) square-based pyramidal geometries for the metal ions, with the water mol-ecule occupying the apical site. In the crystal, the components are linked by O-H⋯O hydrogen bonds and aromatic π-π stacking inter-actions [minimum centroid-centroid separation = 3.537 (2) Å]."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["m1284"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC2971199"],"repository":["biostudies-literature"],"pubmed_title":["Di-μ(4)-succinato-tetra-kis[aqua-phenanthrolinecopper(II)] tetra-nitrate tetra-hydrate."],"pmcid":["PMC2971199"],"pubmed_authors":["Kitiphaisalnont P","Siripaisarnpipat S","Chaichit N"],"additional_accession":[]},"is_claimable":false,"name":"Di-μ(4)-succinato-tetra-kis[aqua-phenanthrolinecopper(II)] tetra-nitrate tetra-hydrate.","description":"In the title compound, [Cu(4)(C(4)H(4)O(4))(2)(C(12)H(8)N(2))(4)(H(2)O)(4)](NO(3))(4)·4H(2)O, the complete tetra-cation is generated by crystallographic inversion symmetry. Both unique Cu(2+) ions are coordinated by an N,N'-bidentate phenanthroline mol-ecule, two O-monodentate bis-bridging succinate dianions and a water mol-ecule, resulting in distorted CuN(2)O(3) square-based pyramidal geometries for the metal ions, with the water mol-ecule occupying the apical site. In the crystal, the components are linked by O-H⋯O hydrogen bonds and aromatic π-π stacking inter-actions [minimum centroid-centroid separation = 3.537 (2) Å].","dates":{"release":"2009-01-01T00:00:00Z","publication":"2009 Oct","modification":"2025-04-26T05:17:44.342Z","creation":"2019-03-27T00:00:16Z"},"accession":"S-EPMC2971199","cross_references":{"pubmed":["21578054"],"doi":["10.1107/S1600536809039580"]}}