<HashMap><database>biostudies-literature</database><scores/><additional><omics_type>Unknown</omics_type><volume>65(Pt 11)</volume><submitter>Kitiphaisalnont P</submitter><pubmed_abstract>In the title compound, [Cu(4)(C(4)H(4)O(4))(2)(C(12)H(8)N(2))(4)(H(2)O)(4)](NO(3))(4)·4H(2)O, the complete tetra-cation is generated by crystallographic inversion symmetry. Both unique Cu(2+) ions are coordinated by an N,N'-bidentate phenanthroline mol-ecule, two O-monodentate bis-bridging succinate dianions and a water mol-ecule, resulting in distorted CuN(2)O(3) square-based pyramidal geometries for the metal ions, with the water mol-ecule occupying the apical site. In the crystal, the components are linked by O-H⋯O hydrogen bonds and aromatic π-π stacking inter-actions [minimum centroid-centroid separation = 3.537 (2) Å].</pubmed_abstract><journal>Acta crystallographica. Section E, Structure reports online</journal><pagination>m1284</pagination><full_dataset_link>https://www.ebi.ac.uk/biostudies/studies/S-EPMC2971199</full_dataset_link><repository>biostudies-literature</repository><pubmed_title>Di-μ(4)-succinato-tetra-kis[aqua-phenanthrolinecopper(II)] tetra-nitrate tetra-hydrate.</pubmed_title><pmcid>PMC2971199</pmcid><pubmed_authors>Kitiphaisalnont P</pubmed_authors><pubmed_authors>Siripaisarnpipat S</pubmed_authors><pubmed_authors>Chaichit N</pubmed_authors></additional><is_claimable>false</is_claimable><name>Di-μ(4)-succinato-tetra-kis[aqua-phenanthrolinecopper(II)] tetra-nitrate tetra-hydrate.</name><description>In the title compound, [Cu(4)(C(4)H(4)O(4))(2)(C(12)H(8)N(2))(4)(H(2)O)(4)](NO(3))(4)·4H(2)O, the complete tetra-cation is generated by crystallographic inversion symmetry. Both unique Cu(2+) ions are coordinated by an N,N'-bidentate phenanthroline mol-ecule, two O-monodentate bis-bridging succinate dianions and a water mol-ecule, resulting in distorted CuN(2)O(3) square-based pyramidal geometries for the metal ions, with the water mol-ecule occupying the apical site. In the crystal, the components are linked by O-H⋯O hydrogen bonds and aromatic π-π stacking inter-actions [minimum centroid-centroid separation = 3.537 (2) Å].</description><dates><release>2009-01-01T00:00:00Z</release><publication>2009 Oct</publication><modification>2025-04-26T05:17:44.342Z</modification><creation>2019-03-27T00:00:16Z</creation></dates><accession>S-EPMC2971199</accession><cross_references><pubmed>21578054</pubmed><doi>10.1107/S1600536809039580</doi></cross_references></HashMap>