biostudies-literatureUnknown65(Pt 12)Xie HIn the title complex, [Mn(C(19)H(12)BrN(3)O(2))Cl(C(3)H(7)NO)], the Mn(III) ion is coordinated by two N and two O atoms from the tetra-dentate Schiff base ligand, one O atom from the dimethyl-formamide ligand and a Cl anion in a distorted octa-hedral geometry. In the crystal structure, weak inter-molecular C-H⋯Cl hydrogen bonds link the mol-ecules into centrosymmetric dimers with a short distance of 3.878 (3) Å between the centroids of the aromatic rings.Acta crystallographica. Section E, Structure reports onlinem1671https://www.ebi.ac.uk/biostudies/studies/S-EPMC2972037biostudies-literature{2,2'-[5-Bromo-pyridine-2,3-diylbis(nitrilo-methyl-idyne)]diphenolato}chlorido(dimethyl-formamide)manganese(III).PMC2972037Meng SXie HZhu YBai Pfalse{2,2'-[5-Bromo-pyridine-2,3-diylbis(nitrilo-methyl-idyne)]diphenolato}chlorido(dimethyl-formamide)manganese(III).In the title complex, [Mn(C(19)H(12)BrN(3)O(2))Cl(C(3)H(7)NO)], the Mn(III) ion is coordinated by two N and two O atoms from the tetra-dentate Schiff base ligand, one O atom from the dimethyl-formamide ligand and a Cl anion in a distorted octa-hedral geometry. In the crystal structure, weak inter-molecular C-H⋯Cl hydrogen bonds link the mol-ecules into centrosymmetric dimers with a short distance of 3.878 (3) Å between the centroids of the aromatic rings.2009-01-01T00:00:00Z2009 Nov2025-04-04T21:04:35.354Z2019-03-27T00:36:19ZS-EPMC29720372157867910.1107/S1600536809049484