<HashMap><database>biostudies-literature</database><scores/><additional><omics_type>Unknown</omics_type><volume>65(Pt 12)</volume><submitter>Zhang BS</submitter><pubmed_abstract>The hydro-thermal reaction of SrCO(3) and 2-bromo-benzoic acid in CH(3)OH-H(2)O afforded the Sr(II) title polymeric complex, [Sr(C(7)H(4)BrO(2))(2)(H(2)O)(2)](n). Within the coordination sphere, the Sr(II) ion is located on a crystallographic twofold axis, and is coordinated by eight O atoms from two water mol-ecules and four carboxyl-ate groups of 2-bromo-benzoate ligands in an irregular coordination geometry. Two μ(3)-carboxyl-ate groups of the 2-bromo-benzoate anions bridge two symmetry-related Sr(II) atoms, giving rise to a chain structure extending along [001]. The polymeric chains are connected via O-H⋯O and O-H⋯Br hydrogen bonds inter-actions into a three-dimensional supra-molecular network.</pubmed_abstract><journal>Acta crystallographica. Section E, Structure reports online</journal><pagination>m1500</pagination><full_dataset_link>https://www.ebi.ac.uk/biostudies/studies/S-EPMC2972083</full_dataset_link><repository>biostudies-literature</repository><pubmed_title>catena-Poly[[diaqua-strontium]-bis-(μ-2-bromo-benzoato)-κO,O':O';κO:O,O'].</pubmed_title><pmcid>PMC2972083</pmcid><pubmed_authors>Zhang BS</pubmed_authors></additional><is_claimable>false</is_claimable><name>catena-Poly[[diaqua-strontium]-bis-(μ-2-bromo-benzoato)-κO,O':O';κO:O,O'].</name><description>The hydro-thermal reaction of SrCO(3) and 2-bromo-benzoic acid in CH(3)OH-H(2)O afforded the Sr(II) title polymeric complex, [Sr(C(7)H(4)BrO(2))(2)(H(2)O)(2)](n). Within the coordination sphere, the Sr(II) ion is located on a crystallographic twofold axis, and is coordinated by eight O atoms from two water mol-ecules and four carboxyl-ate groups of 2-bromo-benzoate ligands in an irregular coordination geometry. Two μ(3)-carboxyl-ate groups of the 2-bromo-benzoate anions bridge two symmetry-related Sr(II) atoms, giving rise to a chain structure extending along [001]. The polymeric chains are connected via O-H⋯O and O-H⋯Br hydrogen bonds inter-actions into a three-dimensional supra-molecular network.</description><dates><release>2009-01-01T00:00:00Z</release><publication>2009 Nov</publication><modification>2025-04-04T21:04:24.413Z</modification><creation>2019-03-27T00:36:19Z</creation></dates><accession>S-EPMC2972083</accession><cross_references><pubmed>21578551</pubmed><doi>10.1107/S1600536809045395</doi></cross_references></HashMap>