{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["65(Pt 12)"],"submitter":["Venter JA"],"pubmed_abstract":["The title compound, [Rh(C(10)H(7)N(2)O(2))(C(18)H(15)P)(CO)]·(CH(3))(2)CO, is the second structural report of a metal complex formed with the O,O'-C(10)H(7)N(2)O(2) (neocupferrate) ligand. In the crystal structure, the metal centre is surrounded by one carbonyl ligand, one triphenyl-phosphine ligand and the bidentate neocupferrate ligand, forming a distorted square-planar RhCO(2)P coordination set which is best illustrated by the small O-Rh-O bite angle of 77.74 (10)°. There are no classical hydrogen-bond inter-actions observed for this complex."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["m1578"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC2972147"],"repository":["biostudies-literature"],"pubmed_title":["Carbon-yl(N-nitroso-N-oxido-1-naphtylamine-κO,O')(triphenyl-phosphine-κP)rhodium(I) acetone solvate."],"pmcid":["PMC2972147"],"pubmed_authors":["Venter JA","Purcell W","Visser HG","Muller TJ"],"additional_accession":[]},"is_claimable":false,"name":"Carbon-yl(N-nitroso-N-oxido-1-naphtylamine-κO,O')(triphenyl-phosphine-κP)rhodium(I) acetone solvate.","description":"The title compound, [Rh(C(10)H(7)N(2)O(2))(C(18)H(15)P)(CO)]·(CH(3))(2)CO, is the second structural report of a metal complex formed with the O,O'-C(10)H(7)N(2)O(2) (neocupferrate) ligand. In the crystal structure, the metal centre is surrounded by one carbonyl ligand, one triphenyl-phosphine ligand and the bidentate neocupferrate ligand, forming a distorted square-planar RhCO(2)P coordination set which is best illustrated by the small O-Rh-O bite angle of 77.74 (10)°. There are no classical hydrogen-bond inter-actions observed for this complex.","dates":{"release":"2009-01-01T00:00:00Z","publication":"2009 Nov","modification":"2025-04-04T21:04:49.72Z","creation":"2019-03-27T00:36:19Z"},"accession":"S-EPMC2972147","cross_references":{"pubmed":["21578610"],"doi":["10.1107/S1600536809047321"]}}