biostudies-literatureUnknown65(Pt 12)Venter JAThe title compound, [Rh(C(10)H(7)N(2)O(2))(C(18)H(15)P)(CO)]·(CH(3))(2)CO, is the second structural report of a metal complex formed with the O,O'-C(10)H(7)N(2)O(2) (neocupferrate) ligand. In the crystal structure, the metal centre is surrounded by one carbonyl ligand, one triphenyl-phosphine ligand and the bidentate neocupferrate ligand, forming a distorted square-planar RhCO(2)P coordination set which is best illustrated by the small O-Rh-O bite angle of 77.74 (10)°. There are no classical hydrogen-bond inter-actions observed for this complex.Acta crystallographica. Section E, Structure reports onlinem1578https://www.ebi.ac.uk/biostudies/studies/S-EPMC2972147biostudies-literatureCarbon-yl(N-nitroso-N-oxido-1-naphtylamine-κO,O')(triphenyl-phosphine-κP)rhodium(I) acetone solvate.PMC2972147Venter JAPurcell WVisser HGMuller TJfalseCarbon-yl(N-nitroso-N-oxido-1-naphtylamine-κO,O')(triphenyl-phosphine-κP)rhodium(I) acetone solvate.The title compound, [Rh(C(10)H(7)N(2)O(2))(C(18)H(15)P)(CO)]·(CH(3))(2)CO, is the second structural report of a metal complex formed with the O,O'-C(10)H(7)N(2)O(2) (neocupferrate) ligand. In the crystal structure, the metal centre is surrounded by one carbonyl ligand, one triphenyl-phosphine ligand and the bidentate neocupferrate ligand, forming a distorted square-planar RhCO(2)P coordination set which is best illustrated by the small O-Rh-O bite angle of 77.74 (10)°. There are no classical hydrogen-bond inter-actions observed for this complex.2009-01-01T00:00:00Z2009 Nov2025-04-04T21:04:49.72Z2019-03-27T00:36:19ZS-EPMC29721472157861010.1107/S1600536809047321