{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["65(Pt 8)"],"submitter":["Miao J"],"pubmed_abstract":["In the title compound, [Cu(C(12)H(9)N(2)O)(2)], the Cu(II) atom lies on a crystallographic inversion center and has a nearly square-planar geometry. The Cu(II) center coordinates to the phenolic O and azomethine N atoms of the two symmetry-related 2-[(2-pyrid-yl)imino-meth-yl]phenolate ligands. The pyridyl N atoms do not coordinate to the Cu(II) atom but participate in intra-molecular C-H⋯N hydrogen bonding. π-π stacking between the benzene rings and between the pyridyl rings [centroid-centroid distances 3.8142 (5) and 3.8142 (5) Å, respectively] links the mol-ecules into a chain propagating parallel to [100]."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["m904"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC2977229"],"repository":["biostudies-literature"],"pubmed_title":["Bis{2-[(2-pyrid-yl)imino-meth-yl]phenolato}copper(II)."],"pmcid":["PMC2977229"],"pubmed_authors":["Wang D","Chen H","Zhao Z","Miao J","Nie Y"],"additional_accession":[]},"is_claimable":false,"name":"Bis{2-[(2-pyrid-yl)imino-meth-yl]phenolato}copper(II).","description":"In the title compound, [Cu(C(12)H(9)N(2)O)(2)], the Cu(II) atom lies on a crystallographic inversion center and has a nearly square-planar geometry. The Cu(II) center coordinates to the phenolic O and azomethine N atoms of the two symmetry-related 2-[(2-pyrid-yl)imino-meth-yl]phenolate ligands. The pyridyl N atoms do not coordinate to the Cu(II) atom but participate in intra-molecular C-H⋯N hydrogen bonding. π-π stacking between the benzene rings and between the pyridyl rings [centroid-centroid distances 3.8142 (5) and 3.8142 (5) Å, respectively] links the mol-ecules into a chain propagating parallel to [100].","dates":{"release":"2009-01-01T00:00:00Z","publication":"2009 Jul","modification":"2025-04-05T00:32:36.224Z","creation":"2019-03-27T00:00:19Z"},"accession":"S-EPMC2977229","cross_references":{"pubmed":["21583364"],"doi":["10.1107/S1600536809026051"]}}