<HashMap><database>biostudies-literature</database><scores/><additional><omics_type>Unknown</omics_type><volume>65(Pt 8)</volume><submitter>Jiang J</submitter><pubmed_abstract>In the title compound, [Co(H(2)O)(6)][Ni(C(12)H(11)N(2)O(5))](2)·6H(2)O, the Ni(II) atom has a nearly square-planar coordination with two N and two O atoms of the N-(4-meth-oxy-2-oxidobenzyl-idene)glycylglycinate Schiff base ligand (L(3-)). The Co(II) atom sits on an inversion center and is coordinated to six aqua ligands in a slightly distorted octa-hedral geometry. The [Co(H(2)O)(6)](2+) cations and [NiL](-) anions form columns along the a axis by O-H?O hydrogen bonds. Additional hydrogen bonds between the uncoordinated and coordinated water molecules help to consolidate the crystal packing.</pubmed_abstract><journal>Acta crystallographica. Section E, Structure reports online</journal><pagination>m952</pagination><full_dataset_link>https://www.ebi.ac.uk/biostudies/studies/S-EPMC2977345</full_dataset_link><repository>biostudies-literature</repository><pubmed_title>Hexaaqua-cobalt(II) bis-{[N-(4-meth-oxy-2-oxidobenzyl-idene)glycylglycinato]nickel(II)} hexa-hydrate.</pubmed_title><pmcid>PMC2977345</pmcid><pubmed_authors>Jiang J</pubmed_authors><pubmed_authors>Lu Y</pubmed_authors><pubmed_authors>Yuan L</pubmed_authors><pubmed_authors>Liu W</pubmed_authors></additional><is_claimable>false</is_claimable><name>Hexaaqua-cobalt(II) bis-{[N-(4-meth-oxy-2-oxidobenzyl-idene)glycylglycinato]nickel(II)} hexa-hydrate.</name><description>In the title compound, [Co(H(2)O)(6)][Ni(C(12)H(11)N(2)O(5))](2)·6H(2)O, the Ni(II) atom has a nearly square-planar coordination with two N and two O atoms of the N-(4-meth-oxy-2-oxidobenzyl-idene)glycylglycinate Schiff base ligand (L(3-)). The Co(II) atom sits on an inversion center and is coordinated to six aqua ligands in a slightly distorted octa-hedral geometry. The [Co(H(2)O)(6)](2+) cations and [NiL](-) anions form columns along the a axis by O-H?O hydrogen bonds. Additional hydrogen bonds between the uncoordinated and coordinated water molecules help to consolidate the crystal packing.</description><dates><release>2009-01-01T00:00:00Z</release><publication>2009 Jul</publication><modification>2021-02-21T01:27:25Z</modification><creation>2019-03-27T00:00:19Z</creation></dates><accession>S-EPMC2977345</accession><cross_references><pubmed>21583401</pubmed><doi>10.1107/S1600536809026750</doi></cross_references></HashMap>