<HashMap><database>biostudies-literature</database><scores/><additional><omics_type>Unknown</omics_type><volume>65(Pt 8)</volume><submitter>Thomas Gunaseelan A</submitter><pubmed_abstract>In the title mol-ecule, C(13)H(13)NO, the dihedral angle between the benzene ring and the fused pyrrole ring is 2.03 (5)°. The methyl group at the 3-position has an equatorial orientation. The cyclo-hexene ring adopts an envelope conformation. Three C atoms of the cyclo-hexene ring, with their attached H atoms, and all atoms of the methyl group are disordered over two positions, the site-occupancy factors being 0.883 (2) and 0.117 (2). In the crystal structure, mol-ecules are stabilized by inter-molecular N-H⋯O hydrogen bonds. A C-H⋯π inter-action, involving the benzene ring, is also found.</pubmed_abstract><journal>Acta crystallographica. Section E, Structure reports online</journal><pagination>o1946-7</pagination><full_dataset_link>https://www.ebi.ac.uk/biostudies/studies/S-EPMC2977477</full_dataset_link><repository>biostudies-literature</repository><pubmed_title>3-Methyl-3,4-dihydro-9H-carbazol-1(2H)-one.</pubmed_title><pmcid>PMC2977477</pmcid><pubmed_authors>Thomas Gunaseelan A</pubmed_authors><pubmed_authors>Rajendra Prasad KJ</pubmed_authors><pubmed_authors>Thiruvalluvar A</pubmed_authors><pubmed_authors>Butcher RJ</pubmed_authors><pubmed_authors>Prabakaran K</pubmed_authors></additional><is_claimable>false</is_claimable><name>3-Methyl-3,4-dihydro-9H-carbazol-1(2H)-one.</name><description>In the title mol-ecule, C(13)H(13)NO, the dihedral angle between the benzene ring and the fused pyrrole ring is 2.03 (5)°. The methyl group at the 3-position has an equatorial orientation. The cyclo-hexene ring adopts an envelope conformation. Three C atoms of the cyclo-hexene ring, with their attached H atoms, and all atoms of the methyl group are disordered over two positions, the site-occupancy factors being 0.883 (2) and 0.117 (2). In the crystal structure, mol-ecules are stabilized by inter-molecular N-H⋯O hydrogen bonds. A C-H⋯π inter-action, involving the benzene ring, is also found.</description><dates><release>2009-01-01T00:00:00Z</release><publication>2009 Jul</publication><modification>2025-04-20T03:58:21.755Z</modification><creation>2019-03-27T00:00:20Z</creation></dates><accession>S-EPMC2977477</accession><cross_references><pubmed>21583627</pubmed><doi>10.1107/S1600536809028050</doi></cross_references></HashMap>