<HashMap><database>biostudies-literature</database><scores/><additional><omics_type>Unknown</omics_type><volume>66(Pt 5)</volume><submitter>Salam MA</submitter><pubmed_abstract>The monodeprotonated Schiff base ligand in the title compound, [Sn(CH(3))(C(14)H(19)N(4)S)Cl(2)], N,N',S-chelates to the Sn atom, which is six-coordinated in an octa-hedral environment. The three coordinating atoms along with the methyl C atom comprise a square plane, above and below which are positioned the Cl atoms. The amino group is a hydrogen-bond donor to a Cl atom of an adjacent mol-ecule, the hydrogen bond giving rise to a helical chain extending parallel to [100].</pubmed_abstract><journal>Acta crystallographica. Section E, Structure reports online</journal><pagination>m570</pagination><full_dataset_link>https://www.ebi.ac.uk/biostudies/studies/S-EPMC2979086</full_dataset_link><repository>biostudies-literature</repository><pubmed_title>Dichlorido{4-cyclo-hexyl-1-[1-(2-pyridyl-κN)ethyl-idene]thio-semicarbazidato-κN,S}methyl-tin(IV).</pubmed_title><pmcid>PMC2979086</pmcid><pubmed_authors>Ng SW</pubmed_authors><pubmed_authors>Salam MA</pubmed_authors><pubmed_authors>Affan MA</pubmed_authors><pubmed_authors>Shamsuddin M</pubmed_authors></additional><is_claimable>false</is_claimable><name>Dichlorido{4-cyclo-hexyl-1-[1-(2-pyridyl-κN)ethyl-idene]thio-semicarbazidato-κN,S}methyl-tin(IV).</name><description>The monodeprotonated Schiff base ligand in the title compound, [Sn(CH(3))(C(14)H(19)N(4)S)Cl(2)], N,N',S-chelates to the Sn atom, which is six-coordinated in an octa-hedral environment. The three coordinating atoms along with the methyl C atom comprise a square plane, above and below which are positioned the Cl atoms. The amino group is a hydrogen-bond donor to a Cl atom of an adjacent mol-ecule, the hydrogen bond giving rise to a helical chain extending parallel to [100].</description><dates><release>2010-01-01T00:00:00Z</release><publication>2010 Apr</publication><modification>2025-04-04T14:42:21.083Z</modification><creation>2019-03-27T00:00:22Z</creation></dates><accession>S-EPMC2979086</accession><cross_references><pubmed>21579051</pubmed><doi>10.1107/S1600536810014443</doi></cross_references></HashMap>