{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["66(Pt 5)"],"submitter":["Jenkinson SF"],"pubmed_abstract":["The relative stereochemistry of the title compound, C(10)H(15)N(3)O(5), was confirmed by the crystal structure determin-ation. The absolute configuration was determined from the use of d-lyxonolactone as the starting material. The six-membered ring adopts a boat conformation with the larger azide group, rather than the methyl group, in the bowsprit position. In the crystal structure, a bifurcated inter-molecular O-H⋯O/O-H⋯N hydrogen bond links mol-ecules into chains running parallel to the b axis."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["o1221-2"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC2979260"],"repository":["biostudies-literature"],"pubmed_title":["2-Azido-2-de-oxy-3,4-O-isopropyl-idene-2-C-methyl-d-talono-1,5-lactone."],"pmcid":["PMC2979260"],"pubmed_authors":["Dai N","Fleet GW","Watkin DJ","Jenkinson SF"],"additional_accession":[]},"is_claimable":false,"name":"2-Azido-2-de-oxy-3,4-O-isopropyl-idene-2-C-methyl-d-talono-1,5-lactone.","description":"The relative stereochemistry of the title compound, C(10)H(15)N(3)O(5), was confirmed by the crystal structure determin-ation. The absolute configuration was determined from the use of d-lyxonolactone as the starting material. The six-membered ring adopts a boat conformation with the larger azide group, rather than the methyl group, in the bowsprit position. In the crystal structure, a bifurcated inter-molecular O-H⋯O/O-H⋯N hydrogen bond links mol-ecules into chains running parallel to the b axis.","dates":{"release":"2010-01-01T00:00:00Z","publication":"2010 Apr","modification":"2025-04-04T14:42:48.826Z","creation":"2019-03-27T00:36:34Z"},"accession":"S-EPMC2979260","cross_references":{"pubmed":["21579248"],"doi":["10.1107/S160053681001500X"]}}