<HashMap><database>biostudies-literature</database><scores/><additional><omics_type>Unknown</omics_type><volume>66(Pt 6)</volume><submitter>Rayner MK</submitter><pubmed_abstract>The title compound, {(C(8)H(20)N(2))[PbCl(4)]}(n), crystallizes as an layered inorganic-organic hybrid perovskite-type structure. Corner-sharing PbCl(6) octa-hedra extend parallel to the ac plane. Adjacent layers are staggered relative to one another, with diammonium cations separating these layers. The cations exhibit symmetry and inter-act with the inorganic sheets via N-H⋯Cl hydrogen bonding in the right-angled halogen sub-type of the terminal halide hydrogen-bonding motif.</pubmed_abstract><journal>Acta crystallographica. Section E, Structure reports online</journal><pagination>m659</pagination><full_dataset_link>https://www.ebi.ac.uk/biostudies/studies/S-EPMC2979563</full_dataset_link><repository>biostudies-literature</repository><pubmed_title>Poly[1,4-bis-(ammonio-meth-yl)cyclo-hexane [di-μ-chlorido-dichloridoplumbate(II)]].</pubmed_title><pmcid>PMC2979563</pmcid><pubmed_authors>Billing DG</pubmed_authors><pubmed_authors>Rayner MK</pubmed_authors></additional><is_claimable>false</is_claimable><name>Poly[1,4-bis-(ammonio-meth-yl)cyclo-hexane [di-μ-chlorido-dichloridoplumbate(II)]].</name><description>The title compound, {(C(8)H(20)N(2))[PbCl(4)]}(n), crystallizes as an layered inorganic-organic hybrid perovskite-type structure. Corner-sharing PbCl(6) octa-hedra extend parallel to the ac plane. Adjacent layers are staggered relative to one another, with diammonium cations separating these layers. The cations exhibit symmetry and inter-act with the inorganic sheets via N-H⋯Cl hydrogen bonding in the right-angled halogen sub-type of the terminal halide hydrogen-bonding motif.</description><dates><release>2010-01-01T00:00:00Z</release><publication>2010 May</publication><modification>2025-04-26T21:47:17.603Z</modification><creation>2019-03-27T00:00:24Z</creation></dates><accession>S-EPMC2979563</accession><cross_references><pubmed>21579304</pubmed><doi>10.1107/S1600536810016818</doi></cross_references></HashMap>