{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["66(Pt 6)"],"submitter":["Shi F"],"pubmed_abstract":["The asymmetric unit of the title complex, [Ni(C(16)H(32)N(4))]Br(2)·2H(2)O, contains two [Ni(C(16)H(32)N(4))](2+) cations, four Br(-) anions and four uncoordinated H(2)O mol-ecules. The Ni atoms are in a slightly distorted square-planar coordination by the four macrocyclic N atoms, which are almost coplanar [N-N-N-N torsion angles of 2.97 (6) and 3.12 (7)°]. In the crystal, a network of N-H⋯Br, O-H⋯Br and N-H⋯O hydrogen bonds leads to the formation of a chain structure."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["m665-6"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC2979623"],"repository":["biostudies-literature"],"pubmed_title":["meso-[5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetra-azacyclo-tetra-deca-1(14),7-diene]nickel(II) dibromide dihydrate."],"pmcid":["PMC2979623"],"pubmed_authors":["Rong R","Shi F","Chen X","Bao Q"],"additional_accession":[]},"is_claimable":false,"name":"meso-[5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetra-azacyclo-tetra-deca-1(14),7-diene]nickel(II) dibromide dihydrate.","description":"The asymmetric unit of the title complex, [Ni(C(16)H(32)N(4))]Br(2)·2H(2)O, contains two [Ni(C(16)H(32)N(4))](2+) cations, four Br(-) anions and four uncoordinated H(2)O mol-ecules. The Ni atoms are in a slightly distorted square-planar coordination by the four macrocyclic N atoms, which are almost coplanar [N-N-N-N torsion angles of 2.97 (6) and 3.12 (7)°]. In the crystal, a network of N-H⋯Br, O-H⋯Br and N-H⋯O hydrogen bonds leads to the formation of a chain structure.","dates":{"release":"2010-01-01T00:00:00Z","publication":"2010 May","modification":"2025-04-26T21:40:06.162Z","creation":"2019-03-27T00:00:25Z"},"accession":"S-EPMC2979623","cross_references":{"pubmed":["21579309"],"doi":["10.1107/S1600536810016831"]}}