{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["66(Pt 2)"],"submitter":["Niu BH"],"pubmed_abstract":["The title compound, [Mn(C(8)H(7)N(3))(3)](2)[SiMo(12)O(40)]·6H(2)O, consists of an [SiMo(12)O(40)](4-) heteropolyanion, lying on a centre of inversion, and a complex [Mn(C(8)H(7)N(3))(3)](4+) cation. The Mn(II) atom of the cation is hexa-coordinated in a distorted octa-hedral geometry by six N atoms from three chelating 3-(2-pyrid-yl)pyrazole ligands. In the heteropolyanion, the four O atoms of the tetra-hedral SiO(4) group each half-occupy eight sites due to Si lying on the centre of inversion. N-H⋯O and O-H⋯O hydrogen bonding mediated by the water mol-ecules leads to a consolidation of the structure."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["m201"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC2979799"],"repository":["biostudies-literature"],"pubmed_title":["Bis{tris-[3-(2-pyrid-yl)pyrazole]manganese(II)} dodeca-molybdosilicate hexa-hydrate."],"pmcid":["PMC2979799"],"pubmed_authors":["Xi Y","Li T","Wu SX","Niu BH"],"additional_accession":[]},"is_claimable":false,"name":"Bis{tris-[3-(2-pyrid-yl)pyrazole]manganese(II)} dodeca-molybdosilicate hexa-hydrate.","description":"The title compound, [Mn(C(8)H(7)N(3))(3)](2)[SiMo(12)O(40)]·6H(2)O, consists of an [SiMo(12)O(40)](4-) heteropolyanion, lying on a centre of inversion, and a complex [Mn(C(8)H(7)N(3))(3)](4+) cation. The Mn(II) atom of the cation is hexa-coordinated in a distorted octa-hedral geometry by six N atoms from three chelating 3-(2-pyrid-yl)pyrazole ligands. In the heteropolyanion, the four O atoms of the tetra-hedral SiO(4) group each half-occupy eight sites due to Si lying on the centre of inversion. N-H⋯O and O-H⋯O hydrogen bonding mediated by the water mol-ecules leads to a consolidation of the structure.","dates":{"release":"2010-01-01T00:00:00Z","publication":"2010 Jan","modification":"2025-04-26T21:39:24.257Z","creation":"2019-03-27T00:00:56Z"},"accession":"S-EPMC2979799","cross_references":{"pubmed":["21579665"],"doi":["10.1107/S1600536810001492"]}}