{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["66(Pt 2)"],"submitter":["Fairuz ZA"],"pubmed_abstract":["In the crystal structure of the title binuclear complex, [Cu(2)(CH(3)COO)(4)(C(13)H(14)N(2))(2)], the four acetate groups each bridge a pair of Cu(II) atoms. The coordination of the metal atoms is distorted square-pyramidal, with the bonding O atoms comprising a square basal plane and the coordinating N atom of the N-heterocycle occupying the apical position. In the two N-hetercycle ligands, the benzene rings are twisted with respect to the pyridine rings, making dihedral angles of 53.1 (2) and 54.2 (2)°. Intra-molecular N-H⋯O hydrogen bonding is present between the imino and carb-oxy groups. The crystal studied was a non-merohedral twin with a minor twin component of 21.4%."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["m165"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC2979871"],"repository":["biostudies-literature"],"pubmed_title":["Tetra-μ-acetato-κO:O'-bis-{[4-methyl-2-(m-tolyl-amino)pyridine-κN]copper(II)}."],"pmcid":["PMC2979871"],"pubmed_authors":["Ng SW","Abdullah Z","Fairuz ZA","Aiyub Z"],"additional_accession":[]},"is_claimable":false,"name":"Tetra-μ-acetato-κO:O'-bis-{[4-methyl-2-(m-tolyl-amino)pyridine-κN]copper(II)}.","description":"In the crystal structure of the title binuclear complex, [Cu(2)(CH(3)COO)(4)(C(13)H(14)N(2))(2)], the four acetate groups each bridge a pair of Cu(II) atoms. The coordination of the metal atoms is distorted square-pyramidal, with the bonding O atoms comprising a square basal plane and the coordinating N atom of the N-heterocycle occupying the apical position. In the two N-hetercycle ligands, the benzene rings are twisted with respect to the pyridine rings, making dihedral angles of 53.1 (2) and 54.2 (2)°. Intra-molecular N-H⋯O hydrogen bonding is present between the imino and carb-oxy groups. The crystal studied was a non-merohedral twin with a minor twin component of 21.4%.","dates":{"release":"2010-01-01T00:00:00Z","publication":"2010 Jan","modification":"2025-04-26T05:05:59.409Z","creation":"2019-03-27T00:00:56Z"},"accession":"S-EPMC2979871","cross_references":{"pubmed":["21579640"],"doi":["10.1107/S1600536809055858"]}}