<HashMap><database>biostudies-literature</database><scores/><additional><omics_type>Unknown</omics_type><volume>66(Pt 2)</volume><submitter>Meyer N</submitter><pubmed_abstract>In the title mixed solvate, [Au(2)Fe(C(17)H(14)P)(2)Cl(2)]·CHCl(3)·0.5CH(3)(CH(2))(4)CH(3), the hexane solvent mol-ecule is disposed about an inversion centre. The Au atoms exist within nearly ideal linear coordination defined by P,Cl-donor sets, and when viewed down the P⋯P axis the Au atoms are gauche to each other. In the crystal structure, the chloro-form solvent mol-ecule is associated with the complex via a C-H⋯Cl contact, and the hexane solvent mol-ecules occupy voids defined by the remaining components of the structure.</pubmed_abstract><journal>Acta crystallographica. Section E, Structure reports online</journal><pagination>m168-9</pagination><full_dataset_link>https://www.ebi.ac.uk/biostudies/studies/S-EPMC2979891</full_dataset_link><repository>biostudies-literature</repository><pubmed_title>[μ-1,1'-Bis(diphenyl-phosphino)ferro-cene-κP:P']bis-[chloridogold(I)]-chloro-form-hexane (2/2/1).</pubmed_title><pmcid>PMC2979891</pmcid><pubmed_authors>Mohr F</pubmed_authors><pubmed_authors>Tiekink ER</pubmed_authors><pubmed_authors>Meyer N</pubmed_authors></additional><is_claimable>false</is_claimable><name>[μ-1,1'-Bis(diphenyl-phosphino)ferro-cene-κP:P']bis-[chloridogold(I)]-chloro-form-hexane (2/2/1).</name><description>In the title mixed solvate, [Au(2)Fe(C(17)H(14)P)(2)Cl(2)]·CHCl(3)·0.5CH(3)(CH(2))(4)CH(3), the hexane solvent mol-ecule is disposed about an inversion centre. The Au atoms exist within nearly ideal linear coordination defined by P,Cl-donor sets, and when viewed down the P⋯P axis the Au atoms are gauche to each other. In the crystal structure, the chloro-form solvent mol-ecule is associated with the complex via a C-H⋯Cl contact, and the hexane solvent mol-ecules occupy voids defined by the remaining components of the structure.</description><dates><release>2010-01-01T00:00:00Z</release><publication>2010 Jan</publication><modification>2025-04-26T05:07:22.524Z</modification><creation>2019-03-27T00:00:56Z</creation></dates><accession>S-EPMC2979891</accession><cross_references><pubmed>21579643</pubmed><doi>10.1107/S1600536810001418</doi></cross_references></HashMap>