{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["66(Pt 1)"],"submitter":["Chen JX"],"pubmed_abstract":["In the title coordination polymer, [Zn(5)(μ(3)-OH)(2)(1,4-CDC)(4)](n) (1,4-CDCH(2) = 1,4-cyclo-hexa-nedicarboxylic acid) or [Zn(5)(C(8)H(10)O(4))(4)(OH)(2)](n), the asymmetric unit comprises one half of an octa-hedrally coordinated ZnO(6) complex unit (site symmetry ) and two five-coordinate ZnO(5) complex units, together with two μ(3)-bridging hydroxido ligands and four 1,4-CDC ligands (comprising two whole mol-ecules and four inversion-related half-molecules). The ZnO(6) unit consists of four carboxyl-ate O donors (two bridging) and two hydroxido O donors (both bridging three Zn centres) [Zn-O range 2.065 (3)-2.125 (3) Å]. Each of the ZnO(5) units [one capped tetra-hedral, the other square-pyrimidal; Zn-O range 1.928 (3)-2.338 (3) Å] has one hydroxido O donor and four carboxyl O donors from three different 1,4-CDC carboxyl-ate O donors (one bridging). Infinite (ZnO)(n) inorganic chains run parallel to the a axis and are interconnected by the organic ligands into a three-dimensional structure."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["m16-7"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC2980201"],"repository":["biostudies-literature"],"pubmed_title":["Poly[tetra-kis(μ-cyclo-hexa-ne-1,4-di-carboxyl-ato)di-μ-hydroxido-penta-zinc(II)]."],"pmcid":["PMC2980201"],"pubmed_authors":["Meng WW","Chen JX"],"additional_accession":[]},"is_claimable":false,"name":"Poly[tetra-kis(μ-cyclo-hexa-ne-1,4-di-carboxyl-ato)di-μ-hydroxido-penta-zinc(II)].","description":"In the title coordination polymer, [Zn(5)(μ(3)-OH)(2)(1,4-CDC)(4)](n) (1,4-CDCH(2) = 1,4-cyclo-hexa-nedicarboxylic acid) or [Zn(5)(C(8)H(10)O(4))(4)(OH)(2)](n), the asymmetric unit comprises one half of an octa-hedrally coordinated ZnO(6) complex unit (site symmetry ) and two five-coordinate ZnO(5) complex units, together with two μ(3)-bridging hydroxido ligands and four 1,4-CDC ligands (comprising two whole mol-ecules and four inversion-related half-molecules). The ZnO(6) unit consists of four carboxyl-ate O donors (two bridging) and two hydroxido O donors (both bridging three Zn centres) [Zn-O range 2.065 (3)-2.125 (3) Å]. Each of the ZnO(5) units [one capped tetra-hedral, the other square-pyrimidal; Zn-O range 1.928 (3)-2.338 (3) Å] has one hydroxido O donor and four carboxyl O donors from three different 1,4-CDC carboxyl-ate O donors (one bridging). Infinite (ZnO)(n) inorganic chains run parallel to the a axis and are interconnected by the organic ligands into a three-dimensional structure.","dates":{"release":"2009-01-01T00:00:00Z","publication":"2009 Dec","modification":"2025-04-22T20:56:29.122Z","creation":"2019-03-27T00:00:27Z"},"accession":"S-EPMC2980201","cross_references":{"pubmed":["21579917"],"doi":["10.1107/S1600536809051666"]}}