<HashMap><database>biostudies-literature</database><scores/><additional><omics_type>Unknown</omics_type><volume>66(Pt 1)</volume><submitter>Nather C</submitter><pubmed_abstract>The crystal structure of the title compound, [Cd(2)Cl(2)(C(2)H(8)N(2))(4)]Cl(2), consists of binuclear centrosymmetric [Cd(2)(C(2)H(8)N(2))(4)Cl(2)](2+) cations and discrete chloride anions. The Cd(II) cation is coordinated by four N atoms of two ethyl-enediamine ligands and two symmetry-related chloride anions within a distorted CdN(4)Cl(2) octa-hedron. Two Cd(II) cations are connected by two chloride anions via μ(2)-coordination, forming a four-membered Cd(2)Cl(2) ring. The uncoordinated chloride anions are linked to the amino groups via N-H⋯Cl hydrogen bonding. Two C atoms of one of the two crystallographically independent ethyl-enediamine ligands are disordered and were refined using a split model [occupancy ratio 0.674 (9):0.326 (9)].</pubmed_abstract><journal>Acta crystallographica. Section E, Structure reports online</journal><pagination>m98</pagination><full_dataset_link>https://www.ebi.ac.uk/biostudies/studies/S-EPMC2980226</full_dataset_link><repository>biostudies-literature</repository><pubmed_title>Di-μ-chlorido-bis-[bis-(ethyl-enediamine-κN,N')cadmium(II)] dichloride.</pubmed_title><pmcid>PMC2980226</pmcid><pubmed_authors>Nather C</pubmed_authors><pubmed_authors>Jess I</pubmed_authors></additional><is_claimable>false</is_claimable><name>Di-μ-chlorido-bis-[bis-(ethyl-enediamine-κN,N')cadmium(II)] dichloride.</name><description>The crystal structure of the title compound, [Cd(2)Cl(2)(C(2)H(8)N(2))(4)]Cl(2), consists of binuclear centrosymmetric [Cd(2)(C(2)H(8)N(2))(4)Cl(2)](2+) cations and discrete chloride anions. The Cd(II) cation is coordinated by four N atoms of two ethyl-enediamine ligands and two symmetry-related chloride anions within a distorted CdN(4)Cl(2) octa-hedron. Two Cd(II) cations are connected by two chloride anions via μ(2)-coordination, forming a four-membered Cd(2)Cl(2) ring. The uncoordinated chloride anions are linked to the amino groups via N-H⋯Cl hydrogen bonding. Two C atoms of one of the two crystallographically independent ethyl-enediamine ligands are disordered and were refined using a split model [occupancy ratio 0.674 (9):0.326 (9)].</description><dates><release>2009-01-01T00:00:00Z</release><publication>2009 Dec</publication><modification>2025-04-22T20:58:28.882Z</modification><creation>2019-03-27T00:00:29Z</creation></dates><accession>S-EPMC2980226</accession><cross_references><pubmed>21579987</pubmed><doi>10.1107/S1600536809054804</doi></cross_references></HashMap>