{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["66(Pt 4)"],"submitter":["Wang W"],"pubmed_abstract":["The title compound, [UO(2)(C(14)H(8)O(5))(H(2)O)](n), is a polymeric UO(2) complex bridged by 4,4'-oxydibenzoate ligands. One carboxyl-ate group of the bridging ligand chelates a uranyl cation while the other carboxyl-ate group of the ligand bridges two other two uranyl cations, forming a double-chain polymeric structure. The central U(VI) atom is seven-coordin-ated in a distorted UO(7) penta-gonal-bipyramidal geometry. In the crystal structure, O-H⋯O hydrogen bonding links the polymeric chains into a three-dimensional supra-molecular framework. Within the bridging ligand, the two benzene rings are oriented at a dihedral angle of 59.0 (2)°."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["m462"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC2983807"],"repository":["biostudies-literature"],"pubmed_title":["catena-Poly[[aqua-dioxidouranium(VI)]-μ(3)-4,4'-oxydibenzoato]."],"pmcid":["PMC2983807"],"pubmed_authors":["Fan Y","Wang W","Song TY","Zhang DJ","Zhang P"],"additional_accession":[]},"is_claimable":false,"name":"catena-Poly[[aqua-dioxidouranium(VI)]-μ(3)-4,4'-oxydibenzoato].","description":"The title compound, [UO(2)(C(14)H(8)O(5))(H(2)O)](n), is a polymeric UO(2) complex bridged by 4,4'-oxydibenzoate ligands. One carboxyl-ate group of the bridging ligand chelates a uranyl cation while the other carboxyl-ate group of the ligand bridges two other two uranyl cations, forming a double-chain polymeric structure. The central U(VI) atom is seven-coordin-ated in a distorted UO(7) penta-gonal-bipyramidal geometry. In the crystal structure, O-H⋯O hydrogen bonding links the polymeric chains into a three-dimensional supra-molecular framework. Within the bridging ligand, the two benzene rings are oriented at a dihedral angle of 59.0 (2)°.","dates":{"release":"2010-01-01T00:00:00Z","publication":"2010 Mar","modification":"2025-04-19T21:40:15.157Z","creation":"2019-03-27T00:00:32Z"},"accession":"S-EPMC2983807","cross_references":{"pubmed":["21580547"],"doi":["10.1107/S1600536810010639"]}}