{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["66(Pt 7)"],"submitter":["Tsai YF"],"pubmed_abstract":["In the title compound, [N(C(4)H(9))(4)][V(C(23)H(21)NS(3)Si)(2)]·4CH(3)CN, the V(III) atom (site symmetry ) is coordinated by two N,S,S'-tridentate 4,4'-dimethyl-2,2'-(3,7-dimethyl-1H-4,2,1-benzothiaza-siline-1,1-di-yl)dibenzene-thiol-ate ligands in a distorted trans-VN(2)S(4) octa-hedral geometry. The complete cation is generated by crystallographic twofold symmetry, with the V atom lying on the rotation axis. The unusual ligand arose from nucleophilic attack on the coordinated nitrile by the thiol-ate precursor and reduction of nitrile to the imidate."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["m844"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC3006863"],"repository":["biostudies-literature"],"pubmed_title":["Tetra-butyl-ammonium bis-[4,4'-dimethyl-2,2'-(3,7-dimethyl-1H-4,2,1-benzothiaza-siline-1,1-di-yl)dibenzene-thiol-ato]vanadium(III) acetonitrile tetra-solvate."],"pmcid":["PMC3006863"],"pubmed_authors":["Hsu HF","Hsu KF","Wang JC","Tsai YF"],"additional_accession":[]},"is_claimable":false,"name":"Tetra-butyl-ammonium bis-[4,4'-dimethyl-2,2'-(3,7-dimethyl-1H-4,2,1-benzothiaza-siline-1,1-di-yl)dibenzene-thiol-ato]vanadium(III) acetonitrile tetra-solvate.","description":"In the title compound, [N(C(4)H(9))(4)][V(C(23)H(21)NS(3)Si)(2)]·4CH(3)CN, the V(III) atom (site symmetry ) is coordinated by two N,S,S'-tridentate 4,4'-dimethyl-2,2'-(3,7-dimethyl-1H-4,2,1-benzothiaza-siline-1,1-di-yl)dibenzene-thiol-ate ligands in a distorted trans-VN(2)S(4) octa-hedral geometry. The complete cation is generated by crystallographic twofold symmetry, with the V atom lying on the rotation axis. The unusual ligand arose from nucleophilic attack on the coordinated nitrile by the thiol-ate precursor and reduction of nitrile to the imidate.","dates":{"release":"2010-01-01T00:00:00Z","publication":"2010 Jun","modification":"2025-04-26T05:08:37.162Z","creation":"2019-03-27T00:00:34Z"},"accession":"S-EPMC3006863","cross_references":{"pubmed":["21587755"],"doi":["10.1107/S1600536810022014"]}}