<HashMap><database>biostudies-literature</database><scores/><additional><omics_type>Unknown</omics_type><volume>66(Pt 7)</volume><submitter>Gowda BT</submitter><pubmed_abstract>In the title compound, C(10)H(8)N(2)O(5), the mol-ecule is slightly distorted from planarity. The mol-ecular structure is stabilized by two intra-molecular hydrogen bonds. The first is a short O-H⋯O hydrogen bond (H⋯O distance = 1.57 Å) within the maleamic acid unit and the second is a C-H⋯O hydrogen bond (H⋯O distance = 2.24 Å) which connects the amide group with the benzene ring. The nitro group is twisted by 6.2 (2)° out of the plane of the benzene ring. The crystal structure manifests a variety of hydrogen bonding. The packing is dominated by a strong inter-molecular N-H⋯O inter-action which links the mol-ecules into chains running along the b axis. The chains within a plane are further assembled by three additional types of inter-molecular C-H⋯O hydrogen bonds to form a sheet parallel to the (01) plane.</pubmed_abstract><journal>Acta crystallographica. Section E, Structure reports online</journal><pagination>o1671-2</pagination><full_dataset_link>https://www.ebi.ac.uk/biostudies/studies/S-EPMC3007040</full_dataset_link><repository>biostudies-literature</repository><pubmed_title>N-(3-Nitro-phen-yl)maleamic acid.</pubmed_title><pmcid>PMC3007040</pmcid><pubmed_authors>Gowda BT</pubmed_authors><pubmed_authors>Shakuntala K</pubmed_authors><pubmed_authors>Kozisek J</pubmed_authors><pubmed_authors>Tokarcik M</pubmed_authors><pubmed_authors>Fuess H</pubmed_authors></additional><is_claimable>false</is_claimable><name>N-(3-Nitro-phen-yl)maleamic acid.</name><description>In the title compound, C(10)H(8)N(2)O(5), the mol-ecule is slightly distorted from planarity. The mol-ecular structure is stabilized by two intra-molecular hydrogen bonds. The first is a short O-H⋯O hydrogen bond (H⋯O distance = 1.57 Å) within the maleamic acid unit and the second is a C-H⋯O hydrogen bond (H⋯O distance = 2.24 Å) which connects the amide group with the benzene ring. The nitro group is twisted by 6.2 (2)° out of the plane of the benzene ring. The crystal structure manifests a variety of hydrogen bonding. The packing is dominated by a strong inter-molecular N-H⋯O inter-action which links the mol-ecules into chains running along the b axis. The chains within a plane are further assembled by three additional types of inter-molecular C-H⋯O hydrogen bonds to form a sheet parallel to the (01) plane.</description><dates><release>2010-01-01T00:00:00Z</release><publication>2010 Jun</publication><modification>2024-11-12T03:41:58.687Z</modification><creation>2019-03-27T00:01:00Z</creation></dates><accession>S-EPMC3007040</accession><cross_references><pubmed>21587897</pubmed><doi>10.1107/S1600536810022245</doi></cross_references></HashMap>