<HashMap><database>biostudies-literature</database><scores/><additional><omics_type>Unknown</omics_type><volume>66(Pt 8)</volume><submitter>Ahmad Tajidi NS</submitter><pubmed_abstract>The Cu(II) atom in the title salt, [Cu(C(10)H(24)N(4))(H(2)O)(2)](C(6)F(5)CO(2))(2)·2H(2)O, is chelated by the four N atoms of the 1,4,8,11-tetra-aza-cyclo-tetra-decane (cyclam) ligand and is coordinated by two water mol-ecules in a Jahn-Teller-type tetra-gonally distorted octa-hedral geometry. The Cu(II) atom lies on a center of inversion. The cations, anions and uncoordinated water mol-ecules are linked by N-H⋯O and O-H⋯O hydrogen bonds, forming a layer structure parallel to (001).</pubmed_abstract><journal>Acta crystallographica. Section E, Structure reports online</journal><pagination>m889</pagination><full_dataset_link>https://www.ebi.ac.uk/biostudies/studies/S-EPMC3007516</full_dataset_link><repository>biostudies-literature</repository><pubmed_title>Diaqua-(1,4,8,11-tetra-aza-cyclo-tetra-decane-κN,N,N,N)copper(II) bis-(2,3,4,5,6-penta-fluoro-benzoate) dihydrate.</pubmed_title><pmcid>PMC3007516</pmcid><pubmed_authors>Ng SW</pubmed_authors><pubmed_authors>Arifin Z</pubmed_authors><pubmed_authors>Abdullah N</pubmed_authors><pubmed_authors>Ahmad Tajidi NS</pubmed_authors><pubmed_authors>Tan KW</pubmed_authors></additional><is_claimable>false</is_claimable><name>Diaqua-(1,4,8,11-tetra-aza-cyclo-tetra-decane-κN,N,N,N)copper(II) bis-(2,3,4,5,6-penta-fluoro-benzoate) dihydrate.</name><description>The Cu(II) atom in the title salt, [Cu(C(10)H(24)N(4))(H(2)O)(2)](C(6)F(5)CO(2))(2)·2H(2)O, is chelated by the four N atoms of the 1,4,8,11-tetra-aza-cyclo-tetra-decane (cyclam) ligand and is coordinated by two water mol-ecules in a Jahn-Teller-type tetra-gonally distorted octa-hedral geometry. The Cu(II) atom lies on a center of inversion. The cations, anions and uncoordinated water mol-ecules are linked by N-H⋯O and O-H⋯O hydrogen bonds, forming a layer structure parallel to (001).</description><dates><release>2010-01-01T00:00:00Z</release><publication>2010 Jul</publication><modification>2025-04-18T19:28:43.091Z</modification><creation>2019-03-27T00:01:01Z</creation></dates><accession>S-EPMC3007516</accession><cross_references><pubmed>21588134</pubmed><doi>10.1107/S1600536810025705</doi></cross_references></HashMap>