{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["67(Pt 1)"],"submitter":["Nishijima T"],"pubmed_abstract":["In the title compound, C(19)H(14)ClNO(5), the aroyl group is attached to the naphthalene ring system with a non-coplanar configuration. The dihedral angle between naphthalene ring system and benzene ring is 70.62 (6)°. The nitro group is oriented in parallel with the adjacent carbonyl plane. The torsion angle of the carbonyl group and naphthalene ring is 54.68 (19)° (C-C-C-O), and that of nitro group and naphthalene ring is 54.26 (18)° (O-N-C-C). In the crystal, π-π inter-actions between naphthalene systems [centroid-centroid distances = 3.5633 (9), 3,5634 (9), and 3.9758(9) Å], C-H⋯O hydrogen bonds, inter-molecular N-O⋯Cl inter-actions [2.9937 (12) Å] and C-H⋯π contacts are observed."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["o155"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC3050249"],"repository":["biostudies-literature"],"pubmed_title":["(4-Chloro-phen-yl)(2,7-dimeth-oxy-8-nitro-naphthalen-1-yl)methanone."],"pmcid":["PMC3050249"],"pubmed_authors":["Nishijima T","Yonezawa N","Okamoto A","Nagasawa A","Takada T"],"additional_accession":[]},"is_claimable":false,"name":"(4-Chloro-phen-yl)(2,7-dimeth-oxy-8-nitro-naphthalen-1-yl)methanone.","description":"In the title compound, C(19)H(14)ClNO(5), the aroyl group is attached to the naphthalene ring system with a non-coplanar configuration. The dihedral angle between naphthalene ring system and benzene ring is 70.62 (6)°. The nitro group is oriented in parallel with the adjacent carbonyl plane. The torsion angle of the carbonyl group and naphthalene ring is 54.68 (19)° (C-C-C-O), and that of nitro group and naphthalene ring is 54.26 (18)° (O-N-C-C). In the crystal, π-π inter-actions between naphthalene systems [centroid-centroid distances = 3.5633 (9), 3,5634 (9), and 3.9758(9) Å], C-H⋯O hydrogen bonds, inter-molecular N-O⋯Cl inter-actions [2.9937 (12) Å] and C-H⋯π contacts are observed.","dates":{"release":"2010-01-01T00:00:00Z","publication":"2010 Dec","modification":"2025-04-05T00:32:00.361Z","creation":"2019-03-27T00:00:43Z"},"accession":"S-EPMC3050249","cross_references":{"pubmed":["21522662"],"doi":["10.1107/S1600536810051998"]}}