{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["67(Pt 5)"],"submitter":["Chiririwa H"],"pubmed_abstract":["In the title Pd(II) complex, [PdCl(2)(C(22)H(22)NP)]·(CH(3))(2)SO, the Pd(II) atom is coordinated in an NPCl(2) coordination sphere by the N(imino) and P(phosphane) atoms of the ligand and by two Cl(-) ions in a slightly distorted square-planar geometry [r.m.s. deviation = 0.081 (3) Å, plane defined by the four atoms around the Pd atom]. The dimethyl sulfoxide solvent mol-ecules form centrosymmetric dimers due to an inter-molecular C-H⋯O inter-action. The crystal structure is further stabilized through two inter-molecular C-H⋯π inter-actions."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["m608-9"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC3089087"],"repository":["biostudies-literature"],"pubmed_title":["Dichlorido{N-[2-(diphenyl-phosphan-yl)benzyl-idene]isopropyl-amine-κN,P}palladium(II) dimethyl sulfoxide monosolvate."],"pmcid":["PMC3089087"],"pubmed_authors":["Meijboom R","Chiririwa H","Omondi B"],"additional_accession":[]},"is_claimable":false,"name":"Dichlorido{N-[2-(diphenyl-phosphan-yl)benzyl-idene]isopropyl-amine-κN,P}palladium(II) dimethyl sulfoxide monosolvate.","description":"In the title Pd(II) complex, [PdCl(2)(C(22)H(22)NP)]·(CH(3))(2)SO, the Pd(II) atom is coordinated in an NPCl(2) coordination sphere by the N(imino) and P(phosphane) atoms of the ligand and by two Cl(-) ions in a slightly distorted square-planar geometry [r.m.s. deviation = 0.081 (3) Å, plane defined by the four atoms around the Pd atom]. The dimethyl sulfoxide solvent mol-ecules form centrosymmetric dimers due to an inter-molecular C-H⋯O inter-action. The crystal structure is further stabilized through two inter-molecular C-H⋯π inter-actions.","dates":{"release":"2011-01-01T00:00:00Z","publication":"2011 May","modification":"2025-04-05T11:55:43.964Z","creation":"2019-03-26T23:59:20Z"},"accession":"S-EPMC3089087","cross_references":{"pubmed":["21754326"],"doi":["10.1107/S1600536811013936"]}}