{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["67(Pt 4)"],"submitter":["Hao J"],"pubmed_abstract":["The title compound, [Ni(C(15)H(24)NSi)(2)], is a homoleptic metal-η(3)-aza-allyl centrosymmetric complex containing two aza-allyl ligands bound in an η(3)-manner to an Ni(II) atom located on a center of symmetry. The overall coordination about the Ni(II) atom is square-planar. The C and N atoms of the aza-allyl group are sp(2)-hybridized. The uneven Ni-C and Ni-N distances [2.045 (5)/2.060 (6) and 1.916 (5) Å] are influenced by a steric hindering effect from the nearby benzene ring."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["m469"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC3099823"],"repository":["biostudies-literature"],"pubmed_title":["Bis(η-2-tert-butyl-1-trimethyl-silyl-3-phenyl-1-aza-all-yl)nickel(II)."],"pmcid":["PMC3099823"],"pubmed_authors":["Liu H","Yuan HY","Hao J"],"additional_accession":[]},"is_claimable":false,"name":"Bis(η-2-tert-butyl-1-trimethyl-silyl-3-phenyl-1-aza-all-yl)nickel(II).","description":"The title compound, [Ni(C(15)H(24)NSi)(2)], is a homoleptic metal-η(3)-aza-allyl centrosymmetric complex containing two aza-allyl ligands bound in an η(3)-manner to an Ni(II) atom located on a center of symmetry. The overall coordination about the Ni(II) atom is square-planar. The C and N atoms of the aza-allyl group are sp(2)-hybridized. The uneven Ni-C and Ni-N distances [2.045 (5)/2.060 (6) and 1.916 (5) Å] are influenced by a steric hindering effect from the nearby benzene ring.","dates":{"release":"2011-01-01T00:00:00Z","publication":"2011 Apr","modification":"2025-04-04T23:27:25.92Z","creation":"2019-03-26T23:59:22Z"},"accession":"S-EPMC3099823","cross_references":{"pubmed":["21753984"],"doi":["10.1107/S1600536811009469"]}}