biostudies-literatureUnknown67(Pt 4)Hao JThe title compound, [Ni(C(15)H(24)NSi)(2)], is a homoleptic metal-η(3)-aza-allyl centrosymmetric complex containing two aza-allyl ligands bound in an η(3)-manner to an Ni(II) atom located on a center of symmetry. The overall coordination about the Ni(II) atom is square-planar. The C and N atoms of the aza-allyl group are sp(2)-hybridized. The uneven Ni-C and Ni-N distances [2.045 (5)/2.060 (6) and 1.916 (5) Å] are influenced by a steric hindering effect from the nearby benzene ring.Acta crystallographica. Section E, Structure reports onlinem469https://www.ebi.ac.uk/biostudies/studies/S-EPMC3099823biostudies-literatureBis(η-2-tert-butyl-1-trimethyl-silyl-3-phenyl-1-aza-all-yl)nickel(II).PMC3099823Liu HYuan HYHao JfalseBis(η-2-tert-butyl-1-trimethyl-silyl-3-phenyl-1-aza-all-yl)nickel(II).The title compound, [Ni(C(15)H(24)NSi)(2)], is a homoleptic metal-η(3)-aza-allyl centrosymmetric complex containing two aza-allyl ligands bound in an η(3)-manner to an Ni(II) atom located on a center of symmetry. The overall coordination about the Ni(II) atom is square-planar. The C and N atoms of the aza-allyl group are sp(2)-hybridized. The uneven Ni-C and Ni-N distances [2.045 (5)/2.060 (6) and 1.916 (5) Å] are influenced by a steric hindering effect from the nearby benzene ring.2011-01-01T00:00:00Z2011 Apr2025-04-04T23:27:25.92Z2019-03-26T23:59:22ZS-EPMC30998232175398410.1107/S1600536811009469