{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["67(Pt 4)"],"submitter":["Phatchimkun J"],"pubmed_abstract":["In the title compound, [Co(C(12)H(12)N(2))(2)(N(3))(2)]·H(2)O, the Co(II) ion is situated on a crystallographic twofold axis and adopts a distorted octa-hedral geometry with the two dmbpy (dmbpy = 5,5'-dimethyl-2,2'-bipyrid-yl) and the two azido ligands in a cis arrangement. The solvent water mol-ecule and one methyl group of the dmbpy ligand are disordered over two sets of sites in a 1:1 ratio. The crystal structure is stabilized by intra-molecular C-H⋯N(dmbpy) and inter-molecular O-H⋯N(azide) hydrogen bonds."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["m516-7"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC3099828"],"repository":["biostudies-literature"],"pubmed_title":["Diazido-bis-(5,5'-dimethyl-2,2'-bipyridyl-κN,N')cobalt(II) monohydrate."],"pmcid":["PMC3099828"],"pubmed_authors":["Chaichit N","Phatchimkun J"],"additional_accession":[]},"is_claimable":false,"name":"Diazido-bis-(5,5'-dimethyl-2,2'-bipyridyl-κN,N')cobalt(II) monohydrate.","description":"In the title compound, [Co(C(12)H(12)N(2))(2)(N(3))(2)]·H(2)O, the Co(II) ion is situated on a crystallographic twofold axis and adopts a distorted octa-hedral geometry with the two dmbpy (dmbpy = 5,5'-dimethyl-2,2'-bipyrid-yl) and the two azido ligands in a cis arrangement. The solvent water mol-ecule and one methyl group of the dmbpy ligand are disordered over two sets of sites in a 1:1 ratio. The crystal structure is stabilized by intra-molecular C-H⋯N(dmbpy) and inter-molecular O-H⋯N(azide) hydrogen bonds.","dates":{"release":"2011-01-01T00:00:00Z","publication":"2011 Apr","modification":"2025-04-04T23:27:28.134Z","creation":"2019-03-27T00:01:04Z"},"accession":"S-EPMC3099828","cross_references":{"pubmed":["21754020"],"doi":["10.1107/S1600536811011305"]}}