biostudies-literatureUnknown67(Pt 4)Phatchimkun JIn the title compound, [Co(C(12)H(12)N(2))(2)(N(3))(2)]·H(2)O, the Co(II) ion is situated on a crystallographic twofold axis and adopts a distorted octa-hedral geometry with the two dmbpy (dmbpy = 5,5'-dimethyl-2,2'-bipyrid-yl) and the two azido ligands in a cis arrangement. The solvent water mol-ecule and one methyl group of the dmbpy ligand are disordered over two sets of sites in a 1:1 ratio. The crystal structure is stabilized by intra-molecular C-H⋯N(dmbpy) and inter-molecular O-H⋯N(azide) hydrogen bonds.Acta crystallographica. Section E, Structure reports onlinem516-7https://www.ebi.ac.uk/biostudies/studies/S-EPMC3099828biostudies-literatureDiazido-bis-(5,5'-dimethyl-2,2'-bipyridyl-κN,N')cobalt(II) monohydrate.PMC3099828Chaichit NPhatchimkun JfalseDiazido-bis-(5,5'-dimethyl-2,2'-bipyridyl-κN,N')cobalt(II) monohydrate.In the title compound, [Co(C(12)H(12)N(2))(2)(N(3))(2)]·H(2)O, the Co(II) ion is situated on a crystallographic twofold axis and adopts a distorted octa-hedral geometry with the two dmbpy (dmbpy = 5,5'-dimethyl-2,2'-bipyrid-yl) and the two azido ligands in a cis arrangement. The solvent water mol-ecule and one methyl group of the dmbpy ligand are disordered over two sets of sites in a 1:1 ratio. The crystal structure is stabilized by intra-molecular C-H⋯N(dmbpy) and inter-molecular O-H⋯N(azide) hydrogen bonds.2011-01-01T00:00:00Z2011 Apr2025-04-04T23:27:28.134Z2019-03-27T00:01:04ZS-EPMC30998282175402010.1107/S1600536811011305