{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["67(Pt 4)"],"submitter":["Yin RT"],"pubmed_abstract":["In the title compound, [CdBr(2)(C(12)H(19)N(3))], the Cd(II) atom is coordinated by the three N atoms of the (1R,2R)-N-(pyridin-2-ylmeth-yl)cyclo-hexane-1,2-diamine ligand and a bromide ion in the basal plane, and by a second bromide in the apical position. The coordination environment can be described as distorted square pyramidal. The coordination of the enanti-o-pure ligand to the metal atom renders the central N atom chiral with an S configuration, so the complex is enanti-omerically pure and corresponds to the S,R,R diastereoisomer. In the crystal, the mol-ecules are linked via weak N-H⋯Br hydrogen bonds into a chain parallel to the b axis."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["m392"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC3099840"],"repository":["biostudies-literature"],"pubmed_title":["Dibromido[(1R,2R,NS)-N-(pyridin-2-ylmeth-yl)cyclo-hexane-1,2-diamine-κN,N',N'']cadmium."],"pmcid":["PMC3099840"],"pubmed_authors":["Cao Z","Cheng L","Yin RT"],"additional_accession":[]},"is_claimable":false,"name":"Dibromido[(1R,2R,NS)-N-(pyridin-2-ylmeth-yl)cyclo-hexane-1,2-diamine-κN,N',N'']cadmium.","description":"In the title compound, [CdBr(2)(C(12)H(19)N(3))], the Cd(II) atom is coordinated by the three N atoms of the (1R,2R)-N-(pyridin-2-ylmeth-yl)cyclo-hexane-1,2-diamine ligand and a bromide ion in the basal plane, and by a second bromide in the apical position. The coordination environment can be described as distorted square pyramidal. The coordination of the enanti-o-pure ligand to the metal atom renders the central N atom chiral with an S configuration, so the complex is enanti-omerically pure and corresponds to the S,R,R diastereoisomer. In the crystal, the mol-ecules are linked via weak N-H⋯Br hydrogen bonds into a chain parallel to the b axis.","dates":{"release":"2011-01-01T00:00:00Z","publication":"2011 Apr","modification":"2025-04-04T23:26:41.959Z","creation":"2019-03-26T23:59:22Z"},"accession":"S-EPMC3099840","cross_references":{"pubmed":["21753928"],"doi":["10.1107/S1600536811007033"]}}