<HashMap><database>biostudies-literature</database><scores/><additional><omics_type>Unknown</omics_type><volume>67(Pt 4)</volume><submitter>Yin RT</submitter><pubmed_abstract>In the title compound, [CdBr(2)(C(12)H(19)N(3))], the Cd(II) atom is coordinated by the three N atoms of the (1R,2R)-N-(pyridin-2-ylmeth-yl)cyclo-hexane-1,2-diamine ligand and a bromide ion in the basal plane, and by a second bromide in the apical position. The coordination environment can be described as distorted square pyramidal. The coordination of the enanti-o-pure ligand to the metal atom renders the central N atom chiral with an S configuration, so the complex is enanti-omerically pure and corresponds to the S,R,R diastereoisomer. In the crystal, the mol-ecules are linked via weak N-H⋯Br hydrogen bonds into a chain parallel to the b axis.</pubmed_abstract><journal>Acta crystallographica. Section E, Structure reports online</journal><pagination>m392</pagination><full_dataset_link>https://www.ebi.ac.uk/biostudies/studies/S-EPMC3099840</full_dataset_link><repository>biostudies-literature</repository><pubmed_title>Dibromido[(1R,2R,NS)-N-(pyridin-2-ylmeth-yl)cyclo-hexane-1,2-diamine-κN,N',N'']cadmium.</pubmed_title><pmcid>PMC3099840</pmcid><pubmed_authors>Cao Z</pubmed_authors><pubmed_authors>Cheng L</pubmed_authors><pubmed_authors>Yin RT</pubmed_authors></additional><is_claimable>false</is_claimable><name>Dibromido[(1R,2R,NS)-N-(pyridin-2-ylmeth-yl)cyclo-hexane-1,2-diamine-κN,N',N'']cadmium.</name><description>In the title compound, [CdBr(2)(C(12)H(19)N(3))], the Cd(II) atom is coordinated by the three N atoms of the (1R,2R)-N-(pyridin-2-ylmeth-yl)cyclo-hexane-1,2-diamine ligand and a bromide ion in the basal plane, and by a second bromide in the apical position. The coordination environment can be described as distorted square pyramidal. The coordination of the enanti-o-pure ligand to the metal atom renders the central N atom chiral with an S configuration, so the complex is enanti-omerically pure and corresponds to the S,R,R diastereoisomer. In the crystal, the mol-ecules are linked via weak N-H⋯Br hydrogen bonds into a chain parallel to the b axis.</description><dates><release>2011-01-01T00:00:00Z</release><publication>2011 Apr</publication><modification>2025-04-04T23:26:41.959Z</modification><creation>2019-03-26T23:59:22Z</creation></dates><accession>S-EPMC3099840</accession><cross_references><pubmed>21753928</pubmed><doi>10.1107/S1600536811007033</doi></cross_references></HashMap>