{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["67(Pt 4)"],"submitter":["Rizzoli C"],"pubmed_abstract":["In the cation of the title compound, [Pd(C(26)H(19)NO(3)P)(C(26)H(24)P(2))]CF(3)O(3)S·CH(2)Cl(2)·0.5C(6)H(14), the Pd(II) atom has a slightly tetra-hedrally distorted square-planar coordination geometry. The PdC(3)P and PdC(2)P(2) five-membered metallacycles adopt envelope and twist conformations, respectively. In the crystal, inter-molecular C-H⋯O hydrogen bonds link cations and anions into a three-dimensional network. The dichloro-methane solvent mol-ecule is disordered over three orientations with a site-occupancy ratio of 0.5/0.3/0.2. The n-hexane solvent mol-ecule has a crystallographically imposed centre of symmetry."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["m416-7"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC3099852"],"repository":["biostudies-literature"],"pubmed_title":["[1,2-Bis(diphenyl-phosphan-yl)ethane-κP,P']{2-[(4-nitro-benzoyl-meth-yl)diphenyl-phosphan-yl]phenyl-κC,C'}palladium(II) trifluoro-methane-sulfonate-dichloro-methane-n-hexane (1/1/0.5)."],"pmcid":["PMC3099852"],"pubmed_authors":["Rizzoli C","Borzooie F","Karami K"],"additional_accession":[]},"is_claimable":false,"name":"[1,2-Bis(diphenyl-phosphan-yl)ethane-κP,P']{2-[(4-nitro-benzoyl-meth-yl)diphenyl-phosphan-yl]phenyl-κC,C'}palladium(II) trifluoro-methane-sulfonate-dichloro-methane-n-hexane (1/1/0.5).","description":"In the cation of the title compound, [Pd(C(26)H(19)NO(3)P)(C(26)H(24)P(2))]CF(3)O(3)S·CH(2)Cl(2)·0.5C(6)H(14), the Pd(II) atom has a slightly tetra-hedrally distorted square-planar coordination geometry. The PdC(3)P and PdC(2)P(2) five-membered metallacycles adopt envelope and twist conformations, respectively. In the crystal, inter-molecular C-H⋯O hydrogen bonds link cations and anions into a three-dimensional network. The dichloro-methane solvent mol-ecule is disordered over three orientations with a site-occupancy ratio of 0.5/0.3/0.2. The n-hexane solvent mol-ecule has a crystallographically imposed centre of symmetry.","dates":{"release":"2011-01-01T00:00:00Z","publication":"2011 Apr","modification":"2025-04-04T23:26:46.868Z","creation":"2019-03-26T23:59:22Z"},"accession":"S-EPMC3099852","cross_references":{"pubmed":["21753947"],"doi":["10.1107/S1600536811008075"]}}