biostudies-literatureUnknown67(Pt 4)Mohamed SKIn the title comound, C(8)H(8)N(4)S, one of the two independent mol-ecules is essentially planar (r.m.s. deviation = 0.025 Å), while the other is slightly buckled (r.m.s. deviation = 0.131 Å) with the guanidine unit bent out of the plane of the fused-ring system by 16.8 (1)°. In the crystal, inter-molecular N-H⋯N hydrogen bonds between the two independent mol-ecules give rise to a hydrogen-bonded dimer. Addtional weak inter-molecular N-H⋯N hydrogen bonds connect these dimers into chains along [010]. An intra-molecular N-H⋯N hydrogen bond is also observed in each independent mol-ecule.Acta crystallographica. Section E, Structure reports onlineo786https://www.ebi.ac.uk/biostudies/studies/S-EPMC3099861biostudies-literature2-(1,3-Benzothia-zol-2-yl)guanidine.PMC3099861Mohamed SKNg SWEl-Remaily MASoliman AMGurbanov AVfalse2-(1,3-Benzothia-zol-2-yl)guanidine.In the title comound, C(8)H(8)N(4)S, one of the two independent mol-ecules is essentially planar (r.m.s. deviation = 0.025 Å), while the other is slightly buckled (r.m.s. deviation = 0.131 Å) with the guanidine unit bent out of the plane of the fused-ring system by 16.8 (1)°. In the crystal, inter-molecular N-H⋯N hydrogen bonds between the two independent mol-ecules give rise to a hydrogen-bonded dimer. Addtional weak inter-molecular N-H⋯N hydrogen bonds connect these dimers into chains along [010]. An intra-molecular N-H⋯N hydrogen bond is also observed in each independent mol-ecule.2011-01-01T00:00:00Z2011 Apr2025-04-04T23:26:51.315Z2019-03-26T23:59:22ZS-EPMC30998612175407710.1107/S160053681100732X