{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["67(Pt 4)"],"submitter":["Wang HB"],"pubmed_abstract":["In the title compound, C(21)H(28)Cl(2)N(3)O(6), the nitronyl nitroxide ring displays a half-chair conformation, whereas the pyrrolidine ring has an envelope conformation. These two rings are twisted to each other with N-C-C-N torsion angles around the connecting C-C bond of 48.9 (6) and -127.0 (5)°. The benzene ring is nearly perpendicular to the pyrrolidine ring, with torsion angles around the connecting C-C bond of 86.3 (6) and -97.7 (6)°. The crystal structure is stabilized by C-H⋯O and C-H⋯π hydrogen bonds, which build up a three-dimensional network."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["o985-6"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC3099877"],"repository":["biostudies-literature"],"pubmed_title":["(R)-2-[1-(2,6-Dichloro-3,4,5-trimeth-oxy-benzo-yl)pyrrolidin-2-yl]-4,4,5,5-tetra-methyl-4,5-dihydro-1H-imidazole-1-oxyl 3-oxide."],"pmcid":["PMC3099877"],"pubmed_authors":["Tian M","Wang HB","Xiang Z","Sun XL","Jing LL"],"additional_accession":[]},"is_claimable":false,"name":"(R)-2-[1-(2,6-Dichloro-3,4,5-trimeth-oxy-benzo-yl)pyrrolidin-2-yl]-4,4,5,5-tetra-methyl-4,5-dihydro-1H-imidazole-1-oxyl 3-oxide.","description":"In the title compound, C(21)H(28)Cl(2)N(3)O(6), the nitronyl nitroxide ring displays a half-chair conformation, whereas the pyrrolidine ring has an envelope conformation. These two rings are twisted to each other with N-C-C-N torsion angles around the connecting C-C bond of 48.9 (6) and -127.0 (5)°. The benzene ring is nearly perpendicular to the pyrrolidine ring, with torsion angles around the connecting C-C bond of 86.3 (6) and -97.7 (6)°. The crystal structure is stabilized by C-H⋯O and C-H⋯π hydrogen bonds, which build up a three-dimensional network.","dates":{"release":"2011-01-01T00:00:00Z","publication":"2011 Apr","modification":"2025-04-04T23:26:58.755Z","creation":"2019-03-27T00:01:04Z"},"accession":"S-EPMC3099877","cross_references":{"pubmed":["21754243"],"doi":["10.1107/S1600536811010270"]}}