<HashMap><database>biostudies-literature</database><scores/><additional><omics_type>Unknown</omics_type><volume>67(Pt 4)</volume><submitter>Wang HB</submitter><pubmed_abstract>In the title compound, C(21)H(28)Cl(2)N(3)O(6), the nitronyl nitroxide ring displays a half-chair conformation, whereas the pyrrolidine ring has an envelope conformation. These two rings are twisted to each other with N-C-C-N torsion angles around the connecting C-C bond of 48.9 (6) and -127.0 (5)°. The benzene ring is nearly perpendicular to the pyrrolidine ring, with torsion angles around the connecting C-C bond of 86.3 (6) and -97.7 (6)°. The crystal structure is stabilized by C-H⋯O and C-H⋯π hydrogen bonds, which build up a three-dimensional network.</pubmed_abstract><journal>Acta crystallographica. Section E, Structure reports online</journal><pagination>o985-6</pagination><full_dataset_link>https://www.ebi.ac.uk/biostudies/studies/S-EPMC3099877</full_dataset_link><repository>biostudies-literature</repository><pubmed_title>(R)-2-[1-(2,6-Dichloro-3,4,5-trimeth-oxy-benzo-yl)pyrrolidin-2-yl]-4,4,5,5-tetra-methyl-4,5-dihydro-1H-imidazole-1-oxyl 3-oxide.</pubmed_title><pmcid>PMC3099877</pmcid><pubmed_authors>Tian M</pubmed_authors><pubmed_authors>Wang HB</pubmed_authors><pubmed_authors>Xiang Z</pubmed_authors><pubmed_authors>Sun XL</pubmed_authors><pubmed_authors>Jing LL</pubmed_authors></additional><is_claimable>false</is_claimable><name>(R)-2-[1-(2,6-Dichloro-3,4,5-trimeth-oxy-benzo-yl)pyrrolidin-2-yl]-4,4,5,5-tetra-methyl-4,5-dihydro-1H-imidazole-1-oxyl 3-oxide.</name><description>In the title compound, C(21)H(28)Cl(2)N(3)O(6), the nitronyl nitroxide ring displays a half-chair conformation, whereas the pyrrolidine ring has an envelope conformation. These two rings are twisted to each other with N-C-C-N torsion angles around the connecting C-C bond of 48.9 (6) and -127.0 (5)°. The benzene ring is nearly perpendicular to the pyrrolidine ring, with torsion angles around the connecting C-C bond of 86.3 (6) and -97.7 (6)°. The crystal structure is stabilized by C-H⋯O and C-H⋯π hydrogen bonds, which build up a three-dimensional network.</description><dates><release>2011-01-01T00:00:00Z</release><publication>2011 Apr</publication><modification>2025-04-04T23:26:58.755Z</modification><creation>2019-03-27T00:01:04Z</creation></dates><accession>S-EPMC3099877</accession><cross_references><pubmed>21754243</pubmed><doi>10.1107/S1600536811010270</doi></cross_references></HashMap>