{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["67(Pt 7)"],"submitter":["Suleiman Gwaram N"],"pubmed_abstract":["The asymmetric unit of the title compound, [Cu(NCS)(2)(C(11)H(17)N(3))], consists of two crystallographically independent mol-ecules. In each mol-ecule, the Cu(II) ion is five-coordinated in a distorted square-pyramidal geometry wherein the basal plane is defined by the N,N',N\"-tridentate Schiff base and one N-bound thio-cyanate ligand. The second N-donor thio-cyanate group, located at the apical site, completes the coordination environment. In the crystal, inter-molecular C-H⋯S and C-H⋯N hydrogen bonds link adjacent mol-ecules into infinite layers parallel to the ac plane. Intra-molecular C-H⋯N inter-actions are also observed."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["m930"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC3151817"],"repository":["biostudies-literature"],"pubmed_title":["{N,N-Dimethyl-N'-[1-(2-pyrid-yl)ethyl-idene]ethane-1,2-diamine-κN,N',N''}bis-(thio-cyanato-κN)copper(II)."],"pmcid":["PMC3151817"],"pubmed_authors":["Khaledi H","Suleiman Gwaram N","Mohd Ali H"],"additional_accession":[]},"is_claimable":false,"name":"{N,N-Dimethyl-N'-[1-(2-pyrid-yl)ethyl-idene]ethane-1,2-diamine-κN,N',N''}bis-(thio-cyanato-κN)copper(II).","description":"The asymmetric unit of the title compound, [Cu(NCS)(2)(C(11)H(17)N(3))], consists of two crystallographically independent mol-ecules. In each mol-ecule, the Cu(II) ion is five-coordinated in a distorted square-pyramidal geometry wherein the basal plane is defined by the N,N',N\"-tridentate Schiff base and one N-bound thio-cyanate ligand. The second N-donor thio-cyanate group, located at the apical site, completes the coordination environment. In the crystal, inter-molecular C-H⋯S and C-H⋯N hydrogen bonds link adjacent mol-ecules into infinite layers parallel to the ac plane. Intra-molecular C-H⋯N inter-actions are also observed.","dates":{"release":"2011-01-01T00:00:00Z","publication":"2011 Jul","modification":"2025-04-19T10:00:13.308Z","creation":"2019-03-26T23:59:24Z"},"accession":"S-EPMC3151817","cross_references":{"pubmed":["21836914"],"doi":["10.1107/S1600536811022057"]}}