{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["67(Pt 7)"],"submitter":["Ngan NK"],"pubmed_abstract":["The coordination geometry at the Mo(VI) atom in the title compound, [Mo(C(16)H(14)N(2)O(4))O(2)(C(2)H(6)OS)], is distorted octa-hedral. The phenolate O, imino N, oxide O from the enolized carbonyl group and one of the terminal O atoms form the equatorial plane; the axial positions are occupied by the other terminal O atom of the dioxidomolybdenum group and the donor O atom of DMSO. The O=Mo=O angle is 105.31 (6)°. An intra-molecular O-H⋯N hydrogen bond and weak inter-molecular C-H⋯O hydrogen bonds are present in the structure."],"journal":["Acta crystallographica. Section E, Structure reports online"],"pagination":["m857"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC3152017"],"repository":["biostudies-literature"],"pubmed_title":["cis-(Dimethyl sulfoxide-κO)[N'-(3-eth-oxy-2-oxidobenzyl-idene-κO)-2-hy-droxy-benzohydrazidato-κN',O]dioxido-molybdenum(VI)."],"pmcid":["PMC3152017"],"pubmed_authors":["Ngan NK","Lo KM","Richard Wong CS"],"additional_accession":[]},"is_claimable":false,"name":"cis-(Dimethyl sulfoxide-κO)[N'-(3-eth-oxy-2-oxidobenzyl-idene-κO)-2-hy-droxy-benzohydrazidato-κN',O]dioxido-molybdenum(VI).","description":"The coordination geometry at the Mo(VI) atom in the title compound, [Mo(C(16)H(14)N(2)O(4))O(2)(C(2)H(6)OS)], is distorted octa-hedral. The phenolate O, imino N, oxide O from the enolized carbonyl group and one of the terminal O atoms form the equatorial plane; the axial positions are occupied by the other terminal O atom of the dioxidomolybdenum group and the donor O atom of DMSO. The O=Mo=O angle is 105.31 (6)°. An intra-molecular O-H⋯N hydrogen bond and weak inter-molecular C-H⋯O hydrogen bonds are present in the structure.","dates":{"release":"2011-01-01T00:00:00Z","publication":"2011 Jul","modification":"2025-04-05T09:14:05.307Z","creation":"2019-03-26T23:59:25Z"},"accession":"S-EPMC3152017","cross_references":{"pubmed":["21836856"],"doi":["10.1107/S1600536811020290"]}}